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| Content Provider | World Health Organization (WHO)-Global Index Medicus |
|---|---|
| Author | Wang, Ji-Xiao Wang, Xuan Sun, Qiao Wang, Xin-Yu Wang, Che Xing, Yong-Heng |
| Description | Author Affiliation: Wang JX ( College of Chemistry and Chemical Engineering, Liaoning Normal University, Huanghe Road 850(#), Dalian City 116029, PR China.); Wang C ( College of Chemistry and Chemical Engineering, Liaoning Normal University, Huanghe Road 850(#), Dalian City 116029, PR China.); Wang X ( College of Chemistry and Chemical Engineering, Liaoning Normal University, Huanghe Road 850(#), Dalian City 116029, PR China.); Wang XY ( College of Chemistry and Chemical Engineering, Liaoning Normal University, Huanghe Road 850(#), Dalian City 116029, PR China.); Xing YH ( College of Chemistry and Chemical Engineering, Liaoning Normal University, Huanghe Road 850(#), Dalian City 116029, PR China. Electronic address: xingyongheng2000@163.com.); Sun Q ( Centre for Theoretical and Computational Molecular Science, Australian Institute for Bioengineering and Nanotechnology, The University of Queensland, QLD 4072, Brisbane, Australia. Electronic address: q.sun@uq.edu.au.) |
| Abstract | Two copper complexes, Cu(SCN)(Mpz(∗)T-(EtO)2) (1) (Mpz(∗)T-(EtO)2=L3) and CuCl(H2O)(Mpz(∗)T-O2) (2) (Mpz(∗)T-O2=L4) were synthesized by the reaction of 2,4,6-tri(3,5-dimethylpyrazol-1-yl)-1,3,5-triazine (L1) or 2,4,6-tri(1H-pyrazol-1-yl)-1,3,5-triazine (L2) with CuCl2·2H2O in anhydrous ethanol and methanol, respectively. The complexes were characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis, single crystal X-ray diffraction and X-ray powder diffraction. The structural characterizations and quantum mechanical calculations of the two complexes were analyzed in detail. It was found that an in site reaction occurred during the synthesis process of complexes 1 and 2, likely due to catalytic property of copper ions which leads to the C-N bond cleavage to generate new organic species, namely, Mpz(∗)T-(EtO)2 (L3) and Mpz(∗)T-O2 (L4). |
| ISSN | 13861425 |
| Volume Number | 142 |
| e-ISSN | 18733557 |
| Journal | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy |
| Language | English |
| Publisher | Elsevier |
| Publisher Date | 2015-05-05 |
| Publisher Place | Great Britain (UK) |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Coordination Complexes Chemistry Copper Pyrazoles Triazines Crystallography, X-ray Ligands Models, Molecular Journal Article Research Support, Non-u.s. Gov't Discipline Spectroscopy |
| Content Type | Text |
| Resource Type | Article |
| Subject | Spectroscopy Atomic and Molecular Physics, and Optics Analytical Chemistry Instrumentation |
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