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| Content Provider | World Health Organization (WHO)-Global Index Medicus |
|---|---|
| Author | Tang, Lijun Hou, Shuhua Zhong, Keli He, Ping Bian, Yanjiang |
| Description | Author Affiliation: Tang L ( Department of Chemistry, Bohai University, Jinzhou 121013, China. Electronic address: ljtang@bhu.edu.cn.); He P ( Department of Chemistry, Bohai University, Jinzhou 121013, China.); Zhong K ( Department of Chemistry, Bohai University, Jinzhou 121013, China.); Hou S ( Department of Chemistry, Bohai University, Jinzhou 121013, China.); Bian Y ( Department of Chemistry, Bohai University, Jinzhou 121013, China.) |
| Abstract | A new reactive probe, 1-(benzo[d]thiazol-2-yl)naphthalen-2-yl-picolinate (BTNP), was designed and synthesized. BTNP acts as a highly selective probe to Cu(2+) in DMSO/H2O (7/3, v/v, Tris-HCl 10mM, pH=7.4) solution based on Cu(2+) catalyzed hydrolysis of the picolinate ester moiety in BTNP, which leads to the formation of an ESIPT active product with dual wavelength emission enhancement. The probe also possesses the advantages of simple synthesis, rapid response and high sensitivity. The pseudo-first-order reaction rate constant was calculated to be 0.205min(-1). Moreover, application of BTNP to Cu(2+) detection in living cells and real water samples was also explored. |
| ISSN | 13861425 |
| Journal | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy |
| Volume Number | 169 |
| e-ISSN | 18733557 |
| Language | English |
| Publisher | Elsevier |
| Publisher Date | 2016-12-05 |
| Publisher Place | Great Britain (UK) |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Discipline Spectroscopy |
| Content Type | Text |
| Resource Type | Article |
| Subject | Spectroscopy Atomic and Molecular Physics, and Optics Analytical Chemistry Instrumentation |
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