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| Content Provider | World Health Organization (WHO)-Global Index Medicus |
|---|---|
| Author | Wang, Yaoguang Hu, Lihua Cui, Limei Wei, Qin Yan, Liangguo Gao, Liang Du, Bin Shi, Li |
| Description | Author Affiliation: Wang Y ( Key Laboratory of Chemical Sensing & Analysis in Universities of Shandong, School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, PR China.); Shi L ( Key Laboratory of Chemical Sensing & Analysis in Universities of Shandong, School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, PR China.); Gao L ( Key Laboratory of Chemical Sensing & Analysis in Universities of Shandong, School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, PR China.); Wei Q ( Key Laboratory of Chemical Sensing & Analysis in Universities of Shandong, School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, PR China.); Cui L ( Key Laboratory of Chemical Sensing & Analysis in Universities of Shandong, School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, PR China.); Hu L ( Key Laboratory of Chemical Sensing & Analysis in Universities of Shandong, School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, PR China.); Yan L ( Key Laboratory of Chemical Sensing & Analysis in Universities of Shandong, School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, PR China.); Du B ( Key Laboratory of Chemical Sensing & Analysis in Universities of Shandong, School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, PR China. Electronic address: dubin61@gmail.com.) |
| Abstract | Magnetic hydroxypropyl chitosan/oxidized multiwalled carbon nanotubes (MHC/OMCNTs) composites were fabricated and applied as the adsorbent to study the adsorption characteristic of lead ions in aqueous solution. The results of Fourier transform infrared spectrum (FTIR), X-ray powder diffraction (XRD) and scanning electron microscope (SEM) showed that the MHC/OMCNTs composites were synthesized successfully. The effects of the solution pH and the contact time were investigated, indicating that the optimal pH and contact time were pH 5.0 and 120min, respectively. The removal of lead ions was rather quick and the kinetic adsorption can be well described by pseudo-second-order model. The experimental results showed that the Sips model is more suitable than Langmuir, Freundlich and Dubinin-Radushkevich models. Furthermore, the parameters of the adsorption thermodynamic calculated in this research such as free energy (ΔG, -2.304 to -5.078kJmol(-1)), enthalpy (ΔH, 39.03kJmol(-1)) and entropy (ΔS, 138.7Jmol(-1)K(-1)) indicated that the adsorption process was endothermic and spontaneous. Therefore, the results in this research suggest that the MHC/OMCNTs composites are ideal adsorbent for the removal of lead ions in aqueous solution. |
| ISSN | 00219797 |
| Journal | Journal of Colloid and Interface Science |
| Volume Number | 451 |
| e-ISSN | 10957103 |
| Language | English |
| Publisher | Elsevier |
| Publisher Date | 2015-08-01 |
| Publisher Place | United States |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Discipline Colloid & Interface Science |
| Content Type | Text |
| Resource Type | Article |
| Subject | Surfaces, Coatings and Films Colloid and Surface Chemistry Biomaterials Electronic, Optical and Magnetic Materials |
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