NDLI: The influence of copper on tebuconazole sorption onto soils, humic substances, and ferrihydrite.

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The influence of copper on tebuconazole sorption onto soils, humic substances, and ferrihydrite.

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The influence of copper on tebuconazole sorption onto soils, humic substances, and ferrihydrite.

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Száková, Jirina Bordas, François Cadková, Eva Bollinger, Jean-Claude Komárek, Michael Kaliszová, Regina Vanek, Ales
Description	Country affiliation: Czech Republic Author Affiliation: Cadková E ( Czech University of Life Sciences Prague, Kamýcká 129, 165 21, Prague 6, Czech Republic. kaliszova@af.czu.cz)
Abstract	The aim of this study is to investigate how the presence of Cu influences tebuconazole (Teb) sorption onto contrasting soil types and two important constituents of the soil sorption complex: hydrated Fe oxide and humic substances. Tebuconazole was used in commercial form and as an analytical-grade chemical at different Teb/Cu molar ratios (1:4, 1:1, 4:1, and Teb alone). Increased Cu concentrations had a positive effect on tebuconazole sorption onto most soils and humic substances, probably as a result of Cu-Teb tertiary complexes on the soil surfaces. Tebuconazole sorption increased in the following order of different Teb/Cu ratios 1:4>1:1>4:1>without Cu addition, with the only exception for the Leptosol and ferrihydrite. The highest K f value was observed for humic substances followed by ferrihydrite, the Cambisol, the Arenosol, and the Leptosol. The sorption of analytical-grade tebuconazole onto all matrices was lower, but the addition of Cu supported again tebuconazole sorption. The Teb/Cu ratio with the highest Cu addition (1:4) exhibited the highest K f values in all matrices with the exception of ferrihydrite. The differences in tebuconazole sorption can be attributed to the additives present in the commercial product. This work proved the importance of soil characteristics and composition of the commercially available pesticides together with the presence of Cu on the behavior of tebuconazole in soils.
ISSN	09441344
Issue Number	6
Volume Number	20
e-ISSN	16147499
Journal	Environmental Science and Pollution Research
Language	English
Publisher	Springer
Publisher Date	2013-06-01
Publisher Place	Germany
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Copper Chemistry Ferric Compounds Humic Substances Soil Triazoles Adsorption Chemical Phenomena Pesticides Soil Pollutants Journal Article Research Support, Non-u.s. Gov't Discipline Environmental Science Discipline Environmental Chemistry
Content Type	Text
Resource Type	Article
Subject	Environmental Chemistry Health, Toxicology and Mutagenesis Pollution Medicine

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