NDLI: Effects of metal cations and fulvic acid on the adsorption of ciprofloxacin onto goethite.

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Effects of metal cations and fulvic acid on the adsorption of ciprofloxacin onto goethite.

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Tan, Yinyue Gu, Xueyuan Gu, Cheng Guo, Yong
Description	Author Affiliation: Tan Y ( State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, 163, Xianlin Ave., Nanjing, Jiangsu, 210023, China, tyy200889@126.com.)
Abstract	Ciprofloxacin (CIP) can be strongly adsorbed by ferric oxides, but some influencing factors, such as multivalent cations and soil organic matter, have not been evaluated extensively. In this study, the interaction between CIP and four divalent metals (Ca, Cd, Cu, and Pb) was investigated using potentiometric titration and the results indicated that CIP can bind to the divalent metals in the following affinity order: Cu(II) > Pb(II) > Cd(II) > Ca(II). The effects of metals and fulvic acid (FA) on the adsorption behavior of CIP onto goethite surfaces were also examined using batch experiments. It was found that metal cations enhanced the CIP retention on goethite surfaces in the same order as the affinity order with CIP, indicating that metals likely increased CIP retention through cation bridging. FA was found to promote CIP sorption rather than compete with it, and the coexistence of FA and Cu(II) in the system exhibited an addictive effect with CIP sorption, indicating that they might influence the sorption separately under the studied loading condition. Taken together, our results suggested that the coexistence of divalent cations or soil organic matter will enhance CIP sorption on goethite surfaces, hence reducing its mobility and bioavailability in the environment.
ISSN	09441344
Issue Number	1
Volume Number	22
e-ISSN	16147499
Journal	Environmental Science and Pollution Research
Language	English
Publisher	Springer
Publisher Date	2015-01-01
Publisher Place	Germany
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Benzopyrans Chemistry Ciprofloxacin Iron Compounds Metals Minerals Soil Pollutants Adsorption Cations Cations, Divalent Soil Journal Article Research Support, Non-u.s. Gov't Discipline Environmental Science Discipline Environmental Chemistry
Content Type	Text
Resource Type	Article
Subject	Environmental Chemistry Health, Toxicology and Mutagenesis Pollution Medicine

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