NDLI: Kinetics of tetracycline, oxytetracycline, and chlortetracycline adsorption and desorption on two acid soils.

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Kinetics of tetracycline, oxytetracycline, and chlortetracycline adsorption and desorption on two acid soils.

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Bermúdez-Couso, Alipio Nóvoa-Muñoz, Juan Carlos Álvarez-rodríguez, Esperanza Núñez-Delgado, Avelino Arias-Estévez, Manuel Fernández-Sanjurjo, Maria J. Fernández-Calviño, David
Description	Country affiliation: Denmark Author Affiliation: Fernández-Calviño D ( Department of Plant and Environmental Sciences, University of Copenhagen, Frederiksberg, Denmark.)
Abstract	The purpose of this work was to quantify retention/release of tetracycline, oxytetracycline, and chlortetracycline on two soils, paying attention to sorption kinetics and to implications of the adsorption/desorption processes on transfer of these pollutants to the various environmental compartments. We used the stirred flow chamber (SFC) procedure to achieve this goal. All three antibiotics showed high affinity for both soils, with greater adsorption intensity for soil 1, the one with the highest organic matter and Al and Fe oxides contents. Desorption was always <15%, exhibiting strong hysteresis in the adsorption/desorption processes. Adsorption was adequately modeled using a pseudo first-order equation with just one type of adsorption sites, whereas desorption was better adjusted considering both fast and slow sorption sites. The adsorption maximum (qmax) followed the sequence tetracycline > oxytetracycline > chlortetracycline in soil 1, with similar values for the three antibiotics and the sequence tetracycline > chlortetracycline > oxytetracycline in soil 2. The desorption sequences were oxytetracycline > tetracycline > chlortetracycline in soil 1 and oxytetracycline > chlortetracycline > tetracycline in soil 2. In conclusion, the SFC technique has yielded new kinetic data regarding tetracycline, oxytetracycline, and chlortetracycline adsorption/desorption on soils, indicating that it can be used to shed further light on the retention and transport processes affecting antibiotics on soils and other media, thus increasing knowledge on the behavior and evolution of these pharmaceutical residues in the environment.
ISSN	09441344
Issue Number	1
Volume Number	22
e-ISSN	16147499
Journal	Environmental Science and Pollution Research
Language	English
Publisher	Springer
Publisher Date	2015-01-01
Publisher Place	Germany
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Anti-bacterial Agents Chemistry Chlortetracycline Oxytetracycline Soil Pollutants Soil Tetracycline Adsorption Analysis Hydrogen-ion Concentration Kinetics Journal Article Research Support, Non-u.s. Gov't Discipline Environmental Science Discipline Environmental Chemistry
Content Type	Text
Resource Type	Article
Subject	Environmental Chemistry Health, Toxicology and Mutagenesis Pollution Medicine

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