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| Content Provider | World Health Organization (WHO)-Global Index Medicus |
|---|---|
| Author | Hofmann, Hans-jörg Tomasini, Claudia Huster, Daniel Monari, Magda Angelici, Gaetano Falini, Giuseppe |
| Description | Author Affiliation: Angelici G ( Dipartimento di Chimica G. Ciamician, Alma Mater Studiorum Università di Bologna, Via Selmi 21, 40126 Bologna, Italy.) |
| Abstract | E’ stata sintetizzata la serie di oligomeri $Boc-(L-Phe-D-Oxd)_{n}-OBn$ (Boc=ter-butossi carbonile; Oxd=4-metil-5-carbossiossazolidin-2-one; Bn=benzile) contenenti l′unità L-Phe-D-Oxd ripetuta 2–5 volte. L′oligomero più corto, $Boc-(L-Phe-D-Oxd)_{2}-OBn,$ si aggrega in fase solida e forma un materiale fibroso avente una struttura a foglietto β antiparallelo, in cui le unità oligopeptidiche sono legate fra loro da un solo legame idrogeno. Gli oligomeri superiori mostrano invece un disordine strutturale ed incominciano ad organizzarsi a livello del pentamero. Analisi mediante microscopia ottica ed elettronica indicano che il solo dimero ha carattere cristallino. |
| ISSN | 09476539 |
| e-ISSN | 15213765 |
| Journal | Chemistry - A European Journal |
| Issue Number | 32 |
| Volume Number | 15 |
| Language | English |
| Publisher | Wiley-VCH;ChemPubSoc Europe |
| Publisher Date | 2009-08-10 |
| Publisher Place | Germany |
| Access Restriction | Open |
| Subject Keyword | Nanostructures Chemistry Oligopeptides Oxazolidinones Chemical Synthesis Crystallography, X-Ray Molecular Conformation Molecular Structure Phenylalanine Research Support, Non-U.S. Gov't |
| Content Type | Text |
| Resource Type | Article |
| Subject | Organic Chemistry Catalysis |
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