NDLI: Relationship between Channel and Sorption Properties in Coordination Polymers with Interdigitated Structures

Please wait, while we are loading the content...

Synthesis, Characterization, and Photoinduced Energy and Electron Transfer in a Supramolecular Tetrakis (Ruthenium(II) Phthalocyanine) Perylenediimide Pentad

Controlled Supramolecular Oligomerization of $C_{3}-Symmetrical$ Molecules in Water: The Impact of Hydrophobic Shielding

Lewis Base Catalyzed [4+2] Annulation of Electron-Deficient Chromone-Derived Heterodienes and Acetylenes

Electrophilic carbocyclization of hydroxylated enynes.

Selective Synthesis of $Fe_{7}Se_{8}$ Polyhedra with Exposed High-Index Facets and $Fe_{7}Se_{8}$ Nanorods by a Solvothermal Process in a Binary Solution and Their Collective Intrinsic Properties

Protonation of Water Clusters Induced by Hydroperoxyl Radical Surface Adsorption

Enhancing Gas Adsorption and Separation Capacity through Ligand Functionalization of Microporous Metal–Organic Framework Structures

Immobilization of DNA on Magnetic Microparticles for Mercury Enrichment and Detection with Flow Cytometry

Olefin Metathesis Featuring Ruthenium Indenylidene Complexes with a Sterically Demanding NHC Ligand

Quantum chemical studies of the hydration of Sr2+ in vacuum and aqueous solution.

Selectivity Manipulation of Bicyclization Reactions of 1,5-Bis(1,2-allenylketone)s: Pd versus Rh and Electronic Effect

Relationship between Channel and Sorption Properties in Coordination Polymers with Interdigitated Structures

Towards the Limit of Atropochiral Stability: H-MIOP, an N-Heterocyclic Carbene Precursor and Cationic Analogue of the H-MOP Ligand

Classification of Organic Solvents Revisited by Using the COSMO-RS $Approach^{†}$

Regio- and Stereoselective Construction of Highly Functionalized 3-Benzazepine Skeletons through Ring-Opening Cycloamination Reactions Catalyzed by Gold

Straightforward Synthesis of Bridged Azaoxa Skeletons: Gold-Catalyzed Aminoketalization of Garner’s Aldehyde-Derived Alkynes

The Use of a Bis(phenylpyrazolyl)pyridyl Ligand to Prepare $[Mn_{4}]$ and $[Mn_{10}]$ Cage Complexes

Lanthanide-Containing Photoluminescent Materials: From Hybrid Hydrogel to Inorganic Nanotubes

A Facile Route to Difunctionalized Monosubstituted Octasilsesquioxanes

Synthesis of Redox-Active, Intramolecular Charge-Transfer Chromophores by the [2+2] Cycloaddition of Ethynylated 2H-Cyclohepta[b]furan-2-ones with Tetracyanoethylene

Synthesis and Structures of the $C_{5}Me_{4}SiMe_{3}-Supported$ Polyhydride Complexes over the Full Size Range of the Rare Earth Series

Nitrogen Dynamics and Reactivity of Chiral Aziridines: Generation of Configurationally Stable Aziridinyllithium Compounds

Electron Exchange Columns through Entrapment of a Nickel Cyclam in a Sol–Gel Matrix

Targeted Cellular Uptake and siRNA Silencing by Quantum-Dot Nanoparticles Coated with β-Cyclodextrin Coupled to Amino Acids

Peralkylated barium complexes.

Year: 2011 Volume: 17 Issue: 17

Year: 2011 Volume: 17 Issue: 16

Year: 2011 Volume: 17 Issue: 15

Year: 2011 Volume: 17 Issue: 14

Year: 2011 Volume: 17 Issue: 13

Year: 2011 Volume: 17 Issue: 12

Year: 2011 Volume: 17 Issue: 11

Year: 2011 Volume: 17 Issue: 10

Year: 2011 Volume: 17 Issue: 9

Year: 2011 Volume: 17 Issue: 8

Year: 2011 Volume: 17 Issue: 7

Year: 2011 Volume: 17 Issue: 6

Year: 2011 Volume: 17 Issue: 5

Year: 2011 Volume: 17 Issue: 4

Year: 2011 Volume: 17 Issue: 3

Year: 2011 Volume: 17 Issue: 2

Year: 2011 Volume: 17 Issue: 1

Year: 2010 Volume: 16

Year: 2009 Volume: 15

Year: 2008 Volume: 14

Year: 2007 Volume: 13

Year: 2006 Volume: 12

Year: 2005 Volume: 11

Year: 1997 Volume: 3

Relationship between Channel and Sorption Properties in Coordination Polymers with Interdigitated Structures

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Kitagawa, Susumu Matsuda, Ryotaro Hijikata, Yuh Sugimoto, Masayuki Sato, Hiroshi Horike, Satoshi
Description	Author Affiliation: Hijikata Y ( Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.)
Abstract	Porous coordination polymers constructed from $Zn^{2+}$ and isophthalate with linear bipyridyl-type ligands were synthesized. $[Zn(ip)(bpb)]_{n}$ (CID-21; ip=isophthalate, bpb=1,4-bis(4-pyridyl)benzene), $[Zn(ip)(bpt)]_{n}$ (CID-22; bpt=3,6-bis(4-pyridyl)-1,2,4,5-tetrazine), and $[Zn(ip)(bpa)]_{n}$ (CID-23; bpa=1,4-bis(4-pyridyl)acetylene) all have interdigitated structures of layers and similar void volumes (≈27 %). In these compounds, 1D bottleneck-type channels run along the perpendicular direction of the layer stacking and their properties are strongly dominated by the dipyridyl linker ligands. Because of the difference in packing of 2D layers, CID-21 and CID-22 have relatively rigid porous structures, whereas CID-23 has greater flexibility, as indicated by the results of powder X-ray diffraction studies. The micropores of CID-22 surrounded by tetrazine moieties adsorb polar molecules, such as methanol and water. The higher affinity of CID-22 for water than CID-21 is supported by a theoretical study. The 1D channel of CID-23 is wider than that of the other two compounds, which enables the incorporation of aromatic molecules. This is because the shape of the bpa linker ligand generates a wider pore diameter (8.6 Å). Only CID-23 can adsorb a benzene molecule and the isotherm of benzene has a gate-opening-type profile. This offers proof of the guest accommodation process through large structural transformation from a nonporous to a porous structure. The flexibility and restricted pore space of CID-23, at 298 K, allows only benzene, but not cyclohexane, to enter the channels. The porous structure exhibits clear selectivity for these similar guests. The incorporation of an elongated dipyridyl linker ligand in the 2D coordination layers provides a strategy for the design of microporous compounds with different flexibilities, microporous environments, and separation abilities.
ISSN	09476539
e-ISSN	15213765
Journal	Chemistry - A European Journal
Issue Number	18
Volume Number	17
Language	English
Publisher	Wiley-VCH;ChemPubSoc Europe
Publisher Date	2011-04-26
Publisher Place	Germany
Access Restriction	Open
Subject Keyword	Chemistry
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Catalysis

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Syntheses, Structures and Optical Band Gaps of Two Coordination Polymers with 2D → 3D Polythreaded and Interdigitated Structures

Synthesis, structures, sorption and magnetic properties of coordination polymers based on 3d metal pivalates and polydentate pyridine-type ligands

Structures and sorption properties of the coordination polymers built up of 3d metal carboxylate polynuclear complexes

Synthesis and gas sorption properties of halogen-doped mesoporous chromium(iii) terephthalate

Zn(II) and Co(II) 3D Coordination Polymers Based on 2-Iodoterephtalic Acid and 1,2-bis(4-pyridyl)ethane: Structures and Sorption Properties

Rhenium octahedral clusters in mesoporous MIL-101: luminescence and sorption properties

Coordination Polymers based on calixarene derivatives: Structures and properties

Porous coordination polymers based on carboxylate complexes of 3d metals

Three interpenetrated copper(II) coordination polymers based on a V-shaped ligand: Synthesis, structures, sorption and magnetic properties

Relationship between Channel and Sorption Properties in Coordination Polymers with Interdigitated Structures

Similar Documents

Syntheses, Structures and Optical Band Gaps of Two Coordination Polymers with 2D → 3D Polythreaded and Interdigitated Structures

Synthesis, structures, sorption and magnetic properties of coordination polymers based on 3d metal pivalates and polydentate pyridine-type ligands

Structures and sorption properties of the coordination polymers built up of 3d metal carboxylate polynuclear complexes

Synthesis and gas sorption properties of halogen-doped mesoporous chromium(iii) terephthalate

Zn(II) and Co(II) 3D Coordination Polymers Based on 2-Iodoterephtalic Acid and 1,2-bis(4-pyridyl)ethane: Structures and Sorption Properties

Rhenium octahedral clusters in mesoporous MIL-101: luminescence and sorption properties

Coordination Polymers based on calixarene derivatives: Structures and properties

Porous coordination polymers based on carboxylate complexes of 3d metals

Three interpenetrated copper(II) coordination polymers based on a V-shaped ligand: Synthesis, structures, sorption and magnetic properties

Relationship between Channel and Sorption Properties in Coordination Polymers with Interdigitated Structures