NDLI: In Situ Infrared Study of the Role of PEG in Stabilizing Silica-Supported Amines for $CO

Please wait, while we are loading the content...

Year: 2017 Volume: 10

Year: 2016 Volume: 9

Year: 2010 Volume: 3 Issue: 12

Year: 2010 Volume: 3 Issue: 11

Year: 2010 Volume: 3 Issue: 10

Year: 2010 Volume: 3 Issue: 9

Year: 2010 Volume: 3 Issue: 8

Steam-Stripping for Regeneration of Supported Amine-Based $CO_{2}$ Adsorbents

High-Surface-Area Carbon Molecular Sieves for Selective $CO_{2}$ Adsorption

The Effect of Trivalent Cations on the Performance of $Mg-M-CO_{3}$ Layered Double Hydroxides for High-Temperature $CO_{2}$ Capture

Challenges of Electric Swing Adsorption for $CO_{2}$ Capture

Highly Selective Amino Acid Salt Solutions as Absorption Liquid for $CO_{2}$ Capture in Gas–Liquid Membrane Contactors

A Bio-Metal–Organic Framework for Highly Selective $CO_{2}$ Capture: A Molecular Simulation Study

Aqueous Ethylenediamine for $CO_{2}$ Capture

Computational Comparison of the Reactions of Substituted Amines with $CO_{2}$

The Immobility of $CO_{2}$ in Marine Sediments Beneath 1500 Meters of Water

In Situ Infrared Study of the Role of PEG in Stabilizing Silica-Supported Amines for $CO_{2}$ Capture

Materials and processes for carbon capture and sequestration.

Year: 2010 Volume: 3 Issue: 7

Year: 2010 Volume: 3 Issue: 6

Year: 2010 Volume: 3 Issue: 5

Year: 2010 Volume: 3 Issue: 4

Year: 2010 Volume: 3 Issue: 3

Year: 2010 Volume: 3 Issue: 2

Year: 2010 Volume: 3 Issue: 1

Year: 2009 Volume: 2

Year: 2008 Volume: 1

In Situ Infrared Study of the Role of PEG in Stabilizing Silica-Supported Amines for $CO_{2}$ Capture

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Tanthana, Jak Chuang, Steven S. C.
Description	Country affiliation: United States Author Affiliation: Tanthana J ( FirstEnergy Advanced Energy Research Center, Department of Chemical and Biomolecular Engineering, The University of Akron, OH 44325-3906, USA.)
Abstract	The $CO_{2}$ capture capacity, adsorption mechanism, and degradation characteristics of two sorbents, silica-supported tetraethylenepentamine $(TEPA/SiO_{2})$ and polyethylene-glycol-modified $TEPA/SiO_{2}$ $(PEG/TEPA/SiO_{2}),$ are studied by diffuse reflectance infrared Fourier transform spectroscopy and mass spectrometry. The $CO_{2}$ capture capacities of $TEPA/SiO_{2}$ and $PEG/TEPA/SiO_{2}$ are determined to be 2087 and $1110 μmol CO_{2} g^{−1} sorbent,$ respectively. Both sorbents adsorb $CO_{2}$ as hydrogen-bonding species, $NH_{2}O,$ and carbamate/carboxylate species. The $CO_{2}$ adsorption half-time increases with the number of $CO_{2}$ capture cycles. Infrared results suggest that the increased adsorption half-time is a result of diffusion limitation, caused by accumulation of TEPA and PEG species on the surface of the sorbent particles. The degradation of $TEPA/SiO_{2}$ is found to correlate with the accumulation of carboxylate/carbamic species. The addition of PEG decreases the degradation rate of the sorbent and slows down the formation of carboxylate species. These carboxylate species can block $CO_{2}$ capture on amine $(NH_{2}/NH)$ sites. The stabilizing role of PEG on $TEPA/SiO_{2}$ can be attributed to hydrogen-bonding between TEPA $(NH_{2}/NH)and$ PEG (OH).
File Format	HTM / HTML
ISSN	18645631
Issue Number	8
Volume Number	3
e-ISSN	1864564X
Journal	ChemSusChem
Language	English
Publisher	Wiley-VCH
Publisher Date	2010-08-23
Publisher Place	Germany
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Research Support, U.s. Gov't, Non-p.h.s. Chemistry Amines Spectrophotometry, Infrared Polyethylene Glycols Silicon Dioxide Mass Spectrometry Discipline Sustainable Chemistry Isolation & Purification Carbon Sequestration Carbon Dioxide Journal Article
Content Type	Text
Resource Type	Article
Subject	Energy Environmental Chemistry Materials Science Chemical Engineering

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Spectroscopic Investigation into Oxidative Degradation of Silica-Supported Amine Sorbents for $CO_{2}$ Capture

Steam-Stripping for Regeneration of Supported Amine-Based $CO_{2}$ Adsorbents

In Situ Infrared Spectroscopic Study of Brucite Carbonation in Dry to Water-Saturated Supercritical Carbon Dioxide

Cyclic Stability Testing of Aminated-Silica Solid Sorbent for Post-Combustion $CO_{2}$ Capture

Tailoring Metal–Organic Frameworks for $CO_{2}$ Capture: The Amino Effect

Highly Selective Amino Acid Salt Solutions as Absorption Liquid for $CO_{2}$ Capture in Gas–Liquid Membrane Contactors

Challenges of Electric Swing Adsorption for $CO_{2}$ Capture

Aqueous Ethylenediamine for $CO_{2}$ Capture

Design, Synthesis, and Evaluation of Nonaqueous Silylamines for Efficient $CO_{2}$ Capture

In Situ Infrared Study of the Role of PEG in Stabilizing Silica-Supported Amines for $CO_{2}$ Capture

Similar Documents

Spectroscopic Investigation into Oxidative Degradation of Silica-Supported Amine Sorbents for $CO_{2}$ Capture

Steam-Stripping for Regeneration of Supported Amine-Based $CO_{2}$ Adsorbents

In Situ Infrared Spectroscopic Study of Brucite Carbonation in Dry to Water-Saturated Supercritical Carbon Dioxide

Cyclic Stability Testing of Aminated-Silica Solid Sorbent for Post-Combustion $CO_{2}$ Capture

Tailoring Metal–Organic Frameworks for $CO_{2}$ Capture: The Amino Effect

Highly Selective Amino Acid Salt Solutions as Absorption Liquid for $CO_{2}$ Capture in Gas–Liquid Membrane Contactors

Challenges of Electric Swing Adsorption for $CO_{2}$ Capture

Aqueous Ethylenediamine for $CO_{2}$ Capture

Design, Synthesis, and Evaluation of Nonaqueous Silylamines for Efficient $CO_{2}$ Capture

In Situ Infrared Study of the Role of PEG in Stabilizing Silica-Supported Amines for $CO_{2}$ Capture