NDLI: Hydrolysis of Ammonia Borane as a Hydrogen Source: Fundamental Issues and Potential Solutions Towards Implementation

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Hydrolysis of Ammonia Borane as a Hydrogen Source: Fundamental Issues and Potential Solutions Towards Implementation

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Sanyal, Udishnu Demirci, Umit B. Jagirdar, Balaji R. Miele, Philippe
Description	Country affiliation: India Author Affiliation: Sanyal U ( Department of Inorganic & Physical Chemistry, Indian Institute of Science, Bangalore, India.)
Abstract	In today’s era of energy crisis and global warming, hydrogen has been projected as a sustainable alternative to depleting $CO_{2}-emitting$ fossil fuels. However, its deployment as an energy source is impeded by many issues, one of the most important being storage. Chemical hydrogen storage materials, in particular BN compounds such as ammonia borane, with a potential storage capacity of 19.6 wt % $H_{2}$ and $0.145 kg L^{−1},$ have been intensively studied from the standpoint of addressing the storage issues. Ammonia borane undergoes dehydrogenation through hydrolysis at room temperature in the presence of a catalyst, but its practical implementation is hindered by several problems affecting all of the chemical compounds in the reaction scheme, including ammonia borane, water, borate byproducts, and hydrogen. In this Minireview, we exhaustively survey the state of the art, discuss the fundamental problems, and, where applicable, propose solutions with the prospect of technological applications.
File Format	HTM / HTML
ISSN	18645631
Issue Number	12
Journal	ChemSusChem
Volume Number	4
e-ISSN	1864564X
Language	English
Publisher	Wiley-VCH
Publisher Date	2011-12-16
Publisher Place	Germany
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Energy-generating Resources Hydrolysis Ammonia Research Support, Non-u.s. Gov't Chemistry Hydrogen Discipline Sustainable Chemistry Boranes Review Journal Article
Content Type	Text
Resource Type	Article
Subject	Energy Environmental Chemistry Materials Science Chemical Engineering

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Hydrolysis of Ammonia Borane as a Hydrogen Source: Fundamental Issues and Potential Solutions Towards Implementation

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Hydrolysis of Ammonia Borane as a Hydrogen Source: Fundamental Issues and Potential Solutions Towards Implementation