NDLI: Development of molecularly imprinted polymeric nanofibers by electrospinning and applications to pesticide adsorption.

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Development of molecularly imprinted polymeric nanofibers by electrospinning and applications to pesticide adsorption.

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Ruggieri, F. D'Archivio, A. A. Di Camillo, D. Lozzi, L. Maggi, M. A. Mercorio, R. Santucci, S.
Description	Country affiliation: Italy Author Affiliation: Ruggieri F ( Dipartimento di Scienze Fisiche e Chimiche, Università degli Studi dell' Aquila, Via Vetoio, Coppito, L'Aquila, Italy.)
Abstract	Novel polystyrene-based molecularly imprinted polymer nanofibers were synthesized through the electrospinning technique. The molecularly imprinted polymers were prepared using a non-covalent approach and atrazine as template. For comparison, nonimprinted polymer nanofibers were also synthesized. The morphology of the synthesized nanofibers was characterized using scanning electron microscopy. The adsorption of pesticides, atrazine, atrazine desisopropyl, atraton, carboxin, linuron, and chlorpyrifos was studied under equilibrium (batch) conditions. To describe the adsorption capability of the synthesized polymers, Langmuir and Freundlich models were used. The Freundlich model provided a better mathematical approximation of the sorption characteristic for polymers nanofibers. To evaluate the adsorption capacity in the presence of interferents experiments on river water samples spiked with a mixture of six pesticides were also performed. The results obtained for the highest concentration levels investigated, show a greater amount of pesticide adsorbed on molecularly imprinted polymers and non-imprinted polymers compared to those obtained using commercial stationary phases used as reference.
File Format	HTM / HTML
ISSN	16159306
Issue Number	8
Volume Number	38
e-ISSN	16159314
Journal	Journal of Separation Science
Language	English
Publisher	Wiley-VCH
Publisher Date	2015-05-01
Publisher Place	Germany
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Discipline Analytical Discipline Chemistry Atrazine Analysis Electrochemistry Molecular Imprinting Pesticides Polymers Chemistry Adsorption Chemistry Techniques, Analytical Chromatography Microscopy, Electron, Scanning Models, Theoretical Nanofibers Nanotechnology Solid Phase Extraction Water Pollutants, Chemical Journal Article
Content Type	Text
Resource Type	Article
Subject	Analytical Chemistry Filtration and Separation

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