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| Content Provider | World Health Organization (WHO)-Global Index Medicus |
|---|---|
| Author | Tayade, Kundan Kaur, Amanpreet Tetgure, Sandesh Chaitanya, G. Krishana Singh, Narinder Kuwar, Anil |
| Description | Country affiliation: India Author Affiliation: Tayade K ( School of Chemical Sciences, North Maharashtra University, Jalgaon, India.); Kaur A ( Centre for Nanoscience and Nanotechnology, Panjab University, Chandigarh, India.); Tetgure S ( School of Chemical Sciences, North Maharashtra University, Jalgaon, India.); Chaitanya GK ( School of Chemical Sciences, Swami Ramanand Tirth Marathawada University, Nanded, India.); Singh N ( Department of Chemistry, Indian Institute of Technology, Ropar, Punjab, India.); Kuwar A ( School of Chemical Sciences, North Maharashtra University, Jalgaon, India. Electronic address: kuwaras@gmail.com.) |
| Abstract | The (13E,19E)-N1',N3'-bis[4-(diethylamino)-2-hydroxybenzylidene]malonohydrazide (L) has been developed for the detection of Th(4+) ions using dual channel signalling system. The UV-vis absorbance and fluorescence spectroscopic data revealed the formation of L-Th(4+) complex in 1:1 equilibrium. The density functional theory (DFT) also confirms the optimum binding cavity for the recognition of metal ion. The binding constant computed from different mathematical models for an assembly of L-Th(4+). The detection limit of L for Th(4+) recognition is to a concentration down to 0.1 µM (0.023 µg g(-1)). The present sensing system is also successfully applied for the detection of Th(4+) ion present in soil near nuclear atomic plants. |
| File Format | HTM / HTML |
| ISSN | 00032670 |
| Volume Number | 852 |
| e-ISSN | 18734324 |
| Journal | Analytica Chimica Acta |
| Language | English |
| Publisher | Elsevier |
| Publisher Date | 2014-12-10 |
| Publisher Place | Netherlands |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Discipline Analytical Discipline Chemistry Amides Chemistry Fluorescent Dyes Imines Thorium Analysis Cations Limit Of Detection Models, Molecular Soil Spectrometry, Fluorescence Methods Evaluation Studies Journal Article |
| Content Type | Text |
| Resource Type | Article |
| Subject | Spectroscopy Environmental Chemistry Analytical Chemistry Biochemistry |
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