NDLI: Experimental binary phase diagram of bilayer compounds [n-C$_{ n }$H$_{2n+1}$N(CH$_{3}$)$_{3}$]$_{2}$CoCl$

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Chemical Research in Chinese Universities : Volume 31, Issue 3, June 2015

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Chemical Research in Chinese Universities : Volume 30

Chemical Research in Chinese Universities : Volume 29

Experimental binary phase diagram of bilayer compounds [n-C$_{ n }$H$_{2n+1}$N(CH$_{3}$)$_{3}$]$_{2}$CoCl$_{4}$

Content Provider	Springer Nature Link
Author	Ruan, Bei Sun, Xiaolong Xiong, Yuanyuan Wu, Kezhong Chen, Jing
Copyright Year	2015
Abstract	Compounds [n-C$_{ n }$H$_{2n+1}$N(CH$_{3}$)$_{3}$]$_{2}$CoCl$_{4}$(n=16, C$_{16}$C$_{3}$Co; n=18, C$_{18}$C$_{3}$Co) containing lipid-like bilayers embedded in a crystalline matrix exist in solid-solid phase transition. The low-temperature bilayer structures of the two compounds were organized by neutralizing CoCl 4 2− with alkylammonium ions. Alkyl chains lay parallel to each other and slightly tilted with respect to the normal of the inorganic layers. The adjacent alkyl chains interacted with each other by van der Waals interaction. When the temperature increased, the two compounds underwent a reversible solid-solid phase transformation within 310–330 K. In such a case, the chains showed a large motional freedom, and a disordered phase appeared. The structures can alternatively be viewed as a double layer of alkylammonium ions between CoCl 4 2− sheets and be considered as crystalline models of lipid bilayers. The experimental subsolidus binary phase diagram of [n-C$_{16}$H$_{33}$N(CH$_{3}$)$_{3}$]$_{2}$CoCl$_{4}$-[n-C$_{18}$H$_{37}$N(CH$_{3}$)$_{3}$]$_{2}$CoCl$_{4}$ was constructed over the entire composition range by differential scanning calorimetry and X-ray diffraction technique. Experimental phase diagram indicates one stable intermediate phase [n-C$_{16}$H$_{33}$N(CH$_{3}$)$_{3}$][n-C$_{18}$H$_{37}$N(CH$_{3}$)$_{3}$]CoCl$_{4}$ at $$w_{C_{16} C_3 Co} = 39.89\%$$ and two invariant three-phase equilibria, which shows two eutectoid temperature e$_{1}$ at (316±1) K for $$w_{C_{16} C_3 Co} = 27.35\%$$ and e$_{2}$ at (313±1) K for $$w_{C_{16} C_3 Co} = 59.76\%$$ . These three noticeable solid-solution ranges are α-phase at the left, β-phase at the right, and γ-phase in the middle of the phase diagram.
Starting Page	611
Ending Page	614
Page Count	4
File Format	PDF
ISSN	10059040
Journal	Chemical Research in Chinese Universities
Volume Number	31
Issue Number	4
e-ISSN	22103171
Language	English
Publisher	Jilin University and The Editorial Department of Chemical Research in Chinese Universities
Publisher Date	2015-07-10
Publisher Place	Changchun
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Differential scanning calorimetry Chemistry/Food Science Analytical Chemistry Phase diagram Physical Chemistry Quaternary ammonium tetrachlorometallate Eutectoid temperature Inorganic Chemistry Phase equilibrium Organic Chemistry
Content Type	Text
Resource Type	Article
Subject	Chemistry Education

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Subsolidus binary phase diagram of the bilayer compounds [n-C$_{ n }$H$_{2n+1}$N(CH$_{3}$)$_{3}$]$_{2}$ZnCl$_{4}$ (n = 16, 18)

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Experimental binary phase diagram of bilayer compounds [n-C$_{ n }$H$_{2n+1}$N(CH$_{3}$)$_{3}$]$_{2}$CoCl$_{4}$

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