NDLI: Ultrasound-accelerated selective oxidation of primary aromatic amines to azoxy derivatives with trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane catalyzed by Preyssler acid-mediated nano-TiO$

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Ultrasound-accelerated selective oxidation of primary aromatic amines to azoxy derivatives with trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane catalyzed by Preyssler acid-mediated nano-TiO$_{2}$

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Ultrasound-accelerated selective oxidation of primary aromatic amines to azoxy derivatives with trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane catalyzed by Preyssler acid-mediated nano-TiO$_{2}$

Content Provider	Springer Nature Link
Author	Khatami, Seyed Mola Najminejad, Zohreh Azarifar, Davood
Copyright Year	2013
Abstract	Preyssler-type heteropolyacid supported on TiO$_{2}$ nanoparticles has been explored as an efficient catalyst in selective oxidation of primary aromatic amines to azoxy derivatives using trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane as oxidant. The reactions proceeded smoothly under mild and green ultrasound-accelerated conditions to afford the products in high yields. The catalyst recovered from the reaction mixture exhibits long-term stability with no significant drop in its catalytic activity. .
Starting Page	587
Ending Page	592
Page Count	6
File Format	PDF
ISSN	1735207X
Journal	Journal of the Iranian Chemical Society
Volume Number	11
Issue Number	2
e-ISSN	17352428
Language	English
Publisher	Springer Berlin Heidelberg
Publisher Date	2013-08-21
Publisher Place	Berlin, Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Analytical Chemistry Nano-TiO$_{2}$ Physical Chemistry Trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane Preyssler-type heteropolyacid Azoxy derivative Oxidation Biochemistry Inorganic Chemistry Aromatic amine Organic Chemistry
Content Type	Text
Resource Type	Article
Subject	Chemistry

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Direct oxidative conversion of benzylhalides, -amines, -alcohols, and arylaldehydes to nitriles with trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane activated by NH$_{4}$Br

Regioselective bromination and iodination of aromatic substrates promoted by trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane

Catalyst-free selective oxidation of alcohols to carbonyls using trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane as an efficient oxidant

Mild and efficient oxidation of 2-pyrazolines and isoxazolines by trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxalane–NH4Cl–HOAc in water–MeCN

Mild oxidative aromatization of 1,4-dihydropyridines with trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxalane promoted by ammonium bromide/HOAc in water/MeCN

Mild and efficient oxidation of 2-pyrazolines and isoxazolines by trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxalane–NH$_{4}$Cl–HOAc in water–MeCN

Trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane as a novel and efficient reagent for selective sulfoxidation of sulfides under catalyst-free condition

Facile Epoxidation of α,β-Unsaturated Ketones with trans-3,5-Dihydroperoxy-3,5-dimethyl-1,2-dioxolane as an Efficient Oxidant

Nano TiO$_{2}$-supported Preyssler-type heteropolyacid (nanoTiO$_{2}$/H$_{14}$[NaP$_{5}$W$_{30}$O$_{110}$]): an efficient and re-usable catalyst for the one-pot synthesis of N-acetyl-2-aryl-1,2-dihydro-(4H)-3,1-benzoxazin-4-ones

Ultrasound-accelerated selective oxidation of primary aromatic amines to azoxy derivatives with trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane catalyzed by Preyssler acid-mediated nano-TiO$_{2}$

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Ultrasound-accelerated selective oxidation of primary aromatic amines to azoxy derivatives with trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane catalyzed by Preyssler acid-mediated nano-TiO$_{2}$