NDLI: Preparation and characterization of ceria-Based electrolytes for intermediate temperature solid oxide fuel cells (IT-SOFC)

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Preparation and characterization of ceria-Based electrolytes for intermediate temperature solid oxide fuel cells (IT-SOFC)

Content Provider	Springer Nature Link
Author	Pattabiraman, R. Samson Nesaraj, A. Arul Raj, I.
Copyright Year	2010
Abstract	Solid-oxide fuel cells (SOFCs) can be used for clean, efficient and environment-friendly energy conversion with a variety of fuels at high temperature (1273 K). The high temperature operation accelerates unwanted reactions and creates materials challenges; so, intermediate-temperature SOFCs (IT-SOFCs) have been developed. Reduction of the operating temperature (between 873–1073 K) requires solid electrolyte materials with higher conductivities. In this study, partially substituted ceria as solid electrolyte is experimented systematically for use in solid oxide fuel cells operating below 1073 K (intermediate temperature range). Nine compositions namely, CeO$_{2}$, Ce$_{0.95}$Gd$_{0.05}$O$_{2-δ}$ (CGO9505), Ce$_{0.90}$Gd$_{0.10}$O$_{2-δ}$ (CGO9010), Ce$_{0.85}$Gd$_{0.15}$O$_{2-δ}$ (CGO8515), Ce$_{0.80}$Gd$_{0.20}$O$_{2-δ}$ (CGO8020), Ce$_{0.95}$Sm$_{0.05}$O$_{2-δ}$ (SDC9505), Ce$_{0.90}$Sm$_{0.10}$O$_{2-δ}$ (SDC9010), Ce$_{0.85}$Sm$_{0.15}$O$_{2-δ}$ (SDC8515) and Ce$_{0.80}$Sm$_{0.20}$O$_{2-δ}$ (SDC8020) were synthesized by Glycine Nitrate (GN) combustion technique and investigated. The physical properties and the other relevant features of the data obtained are analyzed with a view to use these alternate electrolyte materials in IT-SOFC.
Starting Page	564
Ending Page	584
Page Count	21
File Format	PDF
ISSN	1735207X
Journal	Journal of the Iranian Chemical Society
Volume Number	7
Issue Number	3
e-ISSN	17352428
Language	English
Publisher	Springer-Verlag
Publisher Date	2010-01-01
Publisher Place	Berlin, Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Combustion synthesis Analytical Chemistry Physical Chemistry Ceria based electrolyte Biochemistry Inorganic Chemistry Solid oxide fuel cell Physical properties Organic Chemistry
Content Type	Text
Resource Type	Article
Subject	Chemistry

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