NDLI: An Investigation of Adsorption Enantioselectivity of Faceted Polycrystalline Platinum and Gold Electrodes

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Arabian Journal for Science and Engineering : Volume 38

Arabian Journal for Science and Engineering : Volume 37

Arabian Journal for Science and Engineering : Volume 36

An Investigation of Adsorption Enantioselectivity of Faceted Polycrystalline Platinum and Gold Electrodes

Content Provider	Springer Nature Link
Author	Hourani, Mohammad Khair Abu Shmeis, Reham M.
Copyright Year	2013
Abstract	The present work presents an investigation of the enantioselectivity of (111) and (100) faceted polycrystalline platinum and gold electrodes. Electrochemical faceting of these polycrystalline electrodes was carried out by application of a suitable square wave that induces preferential dissolution of some crystallographic planes. The chirality of the produced surfaces was investigated by testing the ability of the prepared surfaces to discriminate voltammetrically between some amino acids and sugar enantiomers upon adsorption at the above-mentioned surfaces. The results indicate that all the polycrystalline electrodes were achiral. Faceted platinum and gold electrodes, however, possess some chirality depending on the surface orientation. Pt(111) faceted electrodes were able to discriminate between enantiomers of the investigated phenylalanine and serine. Pt(100) faceted electrodes also were able to discriminate between the investigated enantiomers, but to a lower extent. Faceted gold electrodes showed a similar ability of discrimination between the investigated phenylalanine and serine enantiomers.
Starting Page	123
Ending Page	129
Page Count	7
File Format	PDF
ISSN	13198025
Journal	Arabian Journal for Science and Engineering
Volume Number	39
Issue Number	1
e-ISSN	21914281
Language	English
Publisher	Springer Berlin Heidelberg
Publisher Date	2013-11-07
Publisher Place	Berlin, Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Faceted electrodes Enantioselectivity Gold and platinum electrodes Chiral surfaces Engineering Science
Content Type	Text
Resource Type	Article

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