NDLI: Composite supercapacitor electrodes made of activated carbon/PEDOT:PSS and activated carbon/doped PEDOT

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Composite supercapacitor electrodes made of activated carbon/PEDOT:PSS and activated carbon/doped PEDOT

Content Provider	Springer Nature Link
Author	SONIA, T S MINI, P A SUJITH, KALLURI AVINASH, BALAKRISHNAN NAIR, S V SUBRAMANIAN, K R V
Copyright Year	2013
Abstract	In this paper, we report on the high electrical storage capacity of composite electrodes made from nanoscale activated carbon combined with either poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) or PEDOT doped with multiple dopants such as ammonium persulfate (APS) and dimethyl sulfoxide (DMSO). The composites were fabricated by electropolymerization of the conducting polymers (PEDOT:PSS, doped PEDOT) onto the nanoscale activated carbon backbone, wherein the nanoscale activated carbon was produced by ball-milling followed by chemical and thermal treatments. Activated carbon/PEDOT:PSS yielded capacitance values of 640 F g$^{−1}$ and 26 mF cm$^{−2}$, while activated carbon/doped PEDOT yielded capacitances of 1183 F g$^{−1}$ and 42 mF cm$^{−2}$ at 10 mV s$^{−1}$. This is more than five times the storage capacity previously reported for activated carbon–PEDOT composites. Further, use of multiple dopants in PEDOT improved the storage performance of the composite electrode well over that of PEDOT:PSS. The composite electrodes were characterized for their electrochemical behaviour, structural and morphological details and electronic conductivity and showed promise as high-performance energy storage systems.
Starting Page	547
Ending Page	551
Page Count	5
File Format	PDF
ISSN	02504707
Journal	Bulletin of Materials Science
Volume Number	36
Issue Number	4
e-ISSN	09737669
Language	English
Publisher	Springer India
Publisher Date	2013-08-04
Publisher Institution	Indian Academy of Sciences
Publisher Place	India
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Carbon materials composite materials electrodeposition energy storage and conversion thin films conducting polymers Materials Science Engineering
Content Type	Text
Resource Type	Article
Subject	Mechanics of Materials Materials Science

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