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Redox shuttle additives for chemical overcharge protection in lithium ion batteries

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Redox shuttle additives for chemical overcharge protection in lithium ion batteries

Content Provider	Springer Nature Link
Author	Lee, Doo Yeon Lee, Hyo Sug Kim, Ho Sung Sun, Hee Young Seung, Do Young
Copyright Year	2002
Abstract	We disclosed that a few kinds of aromatic compounds having thianthrene derivatives with acetyl or other functional groups were stable up to about 4.2-4.3 V against lithium. These materials, called redox shuttle, have lately been employed as a chemical overcharge protection agent that consumes the excess current during battery overcharge. They oxidized above 4 V and worked as redox shuttle when introduced into the electrolyte of a Carbon/LiCoO$_{2}$ prismatic battery within less than one hour rate (1C). We also studied thermal properties of batteries containing the above-mentioned materials with ARC (Accelerating Rate Calorimeter). We ascertained that the current supplied over the full charge was not stored, but instantly and quite completely consumed in an oxidation-reduction reaction.
Starting Page	645
Ending Page	652
Page Count	8
File Format	PDF
ISSN	02561115
Journal	Korean Journal of Chemical Engineering
Volume Number	19
Issue Number	4
e-ISSN	19757220
Language	English
Publisher	Springer-Verlag
Publisher Date	2002-01-01
Publisher Place	Berlin, Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Redox Shuttle Thianthrene Derivatives Overcharge Protection Oxidation-reduction ARC (Accelerating Rate Calorimeter) Industrial Chemistry/Chemical Engineering Catalysis Materials Science Biotechnology
Content Type	Text
Resource Type	Article
Subject	Chemistry Chemical Engineering

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