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| Content Provider | Springer Nature Link |
|---|---|
| Author | Cho, Young Gu Hwang, Byung Ha Park, Dae Won Woo, Hee Chul Chung, Jong Shik |
| Copyright Year | 2002 |
| Abstract | The selective oxidation of hydrogen sulfide containing excess water and ammonia was studied over vanadium oxide-based catalysts. The investigation was focused on the role of V$_{2}$O$_{5}$, and phase cooperation between V$_{2}$O$_{5}$ and Bi$_{2}$O$_{3}$ in this reaction. The conversion of H$_{2}$S continued to decrease since V$_{2}$O$_{5}$ was gradually reduced by treatment with H$_{2}$S. The activity of V$_{2}$O$_{5}$ was recovered by contact with oxygen. A strong synergistic phenomenon in catalytic activity was observed for the mechanically mixed catalysts of V$_{2}$O$_{5}$ and Bi$_{2}$O$_{3}$. Temperature-programmed reduction (TPR) and oxidation (TPO) and two bed reaction tests were performed to explain this synergistic effect by the reoxidation ability of Bi$_{2}$O$_{3}$. |
| Starting Page | 611 |
| Ending Page | 616 |
| Page Count | 6 |
| File Format | |
| ISSN | 02561115 |
| Journal | Korean Journal of Chemical Engineering |
| Volume Number | 19 |
| Issue Number | 4 |
| e-ISSN | 19757220 |
| Language | English |
| Publisher | Springer-Verlag |
| Publisher Date | 2002-01-01 |
| Publisher Place | Berlin, Heidelberg |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Hydrogen Sulfide 1Selective Oxidation Phase Cooperation Vanadium Oxide Bismuth Oxide Industrial Chemistry/Chemical Engineering Catalysis Materials Science Biotechnology |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Chemical Engineering |
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