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| Content Provider | Springer Nature Link |
|---|---|
| Author | Domashevskaya, E. P. Terekhov, V. A. Turishchev, S. Yu. Prijimov, A. S. Kharin, A. N. Pariva, E. V. Rumyantseva, N. A. Usoltseva, D. S. Fomenko, Yu. L. Belenko, S. V. |
| Copyright Year | 2015 |
| Abstract | Semi-insulating silicon SIPOS layers are prepared on single-crystal silicon substrates of two orientations Si (111) and Si (100) by chemical-vapor deposition at a reduced pressure in a horizontal hot-wall reactor at a temperature of 638°C and pressure of P = 20 Pa with a silane flow rate of 8 L/h and the addition of nitrous oxide into the reactor environment. Electronic-structure and phase-composition investigations by ultrasoft X-ray emission spectroscopy (USXES) and X-ray diffraction (XRD) methods show that the addition of nitrous-oxide gas into the reactor environment results in the formation of amorphous silicon layers. The layer-by-layer-phase analysis via USXES of the SIPOS samples to a depth of 120 nm without destruction indicates the predominance of oxide phases in the sample surface layers with a thickness of about 10 nm. The general content of unbound and bound oxygen of less than about 10%, below which nanocrystalline silicon is formed with an average particle size of 60–70 nm, can be considered as some conditional crystallization threshold of SIPOS amorphous layers. |
| Starting Page | 1228 |
| Ending Page | 1236 |
| Page Count | 9 |
| File Format | |
| ISSN | 10274510 |
| Journal | Journal of Surface Investigation. X-ray, Synchrotron and Neutron Techniques |
| Volume Number | 9 |
| Issue Number | 6 |
| e-ISSN | 18197094 |
| Language | English |
| Publisher | Pleiades Publishing |
| Publisher Date | 2015-12-06 |
| Publisher Place | Moscow |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | ultrasoft X-ray emission spectroscopy amorphous and nanocrystalline silicon layers atomic and electronic structure low pressure chemical-vapor deposition Surfaces and Interfaces, Thin Films |
| Content Type | Text |
| Resource Type | Article |
| Subject | Nanoscience and Nanotechnology Surfaces, Coatings and Films |
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