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| Content Provider | Springer Nature Link |
|---|---|
| Author | Dewar, Matthew P. Gerlich, Adrian P. |
| Copyright Year | 2012 |
| Abstract | A centrifugally cast 20Cr32Ni1Nb stainless steel manifold in service for 16 years at temperatures ranging from 1073 K to 1123 K (800 °C to 850 °C) has been characterized using scanning electron microscopy (SEM), electron probe micro-analysis (EPMA), auger electron spectroscopy (AES), and X-ray diffraction (XRD). Nb(C,N), M$_{23}$C$_{6}$, and the silicide G-phases (Ni$_{16}$Nb$_{6}$Si$_{7}$) were all identified in a conventional SEM, while the nitride Z-phase (CrNbN) was observed only in AES. M$_{23}$C$_{6}$, Z-phase and G-phase were characterized in XRD. Thermodynamic equilibrium calculations using ThermoCalc Version S, with the TCS Steel and Fe-alloys Database (TCFE6), and Thermotech Ni-based Superalloys Database (TTNI8) were validated by comparing experimental phase fraction results obtained from both EPMA and AES. A computational study looking at variations in the chemical composition of the alloy, and how they affect phase equilibria, was investigated. Increasing the nitrogen concentration is shown to decrease G-phase formation, where it is replaced by other intermetallic phases such as Z-phase and π-phase that do not experience liquation during pre-weld annealing treatments. Suppressing G-phase formation was ultimately determined to be a function of minimizing silicon content, and understabilizing the Nb/(C + 6/7N) ratio. |
| Starting Page | 627 |
| Ending Page | 639 |
| Page Count | 13 |
| File Format | |
| ISSN | 10735623 |
| Journal | Metallurgical and Materials Transactions A |
| Volume Number | 44 |
| Issue Number | 2 |
| e-ISSN | 15431940 |
| Language | English |
| Publisher | Springer US |
| Publisher Date | 2012-10-10 |
| Publisher Place | Boston |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Metallic Materials Characterization and Evaluation of Materials Structural Materials Surfaces and Interfaces, Thin Films Nanotechnology |
| Content Type | Text |
| Resource Type | Article |
| Subject | Mechanics of Materials Metals and Alloys Condensed Matter Physics |
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