NDLI: Direct photo-oxidation of benzene to phenol over Ti/Si binary oxide prepared by sol-gel method

Please wait, while we are loading the content...

Selective oxidation of n-butane over Fe-promoted vanadyl pyrophosphate prepared from modification of nano-sized interlayer of lamellar vanadyl benzylphosphate

Separation of CO$_{2}$ and CH$_{4}$ by a DDR membrane

Hydrotalcite-bound ruthenium as a multifunctional heterogeneous catalyst for one-pot synthesis of α-alkylated nitriles and quinolines

Metal oxide promoted TiO$_{2}$ catalysts for photo-assisted selective catalytic reduction of NO with NH$_{3}$

Preparation of nano-sized Pt metal particles by photo-assisted deposition (PAD) on transparent Ti-containing mesoporous silica thin film

Lewis-type catalytic activity of direct incorporated Zr- and Sn-SBA-16 catalysts

Photoluminescence properties of Ag$_{2}$S semiconductor clusters synthesized in micropores and mesopores

Direct photo-oxidation of benzene to phenol over Ti/Si binary oxide prepared by sol-gel method

Synthesis of one-dimensional microporous todorokite and its catalytic activity in CO oxidation

Charge separation in mesoporous aluminosilicates

Dispersion and states of platinum ions in BEA-zeolite pores: effect of the framework basicity

Effect of HF treatment on the activity of TiO$_{2}$ thin films for photocatalytic water splitting

Visible-light-induced oxidative removal of nitrogen oxides in air by metal chloride-modified titanium (IV) oxide nanoparticles

Liquid-phase hydrogenation of alkenes and aromatic compounds with Pd-loaded oxidized diamond catalyst

In situ diffuse reflectance FT-IR studies of TiO$_{2}$ and Pt/TiO$_{2}$ in photo-oxidation of benzene and ethylene

Effect of synthesis conditions on preparation of mesoporous titania-silica by a modified sol-gel technique using a cationic surfactant

Effects of preparation conditions on the synthesis of nano-sized Ag metal particles by the wet-process using 3-mercapto-propionic acid

Structure of iron and manganese ions substituted in the framework of nanoporous AlPO-5 material

Research on Chemical Intermediates : Volume 34, Issue 4, April 2008

Research on Chemical Intermediates : Volume 34, Issue 2-3, February 2008

Research on Chemical Intermediates : Volume 34, Issue 1, January 2008

Research on Chemical Intermediates : Volume 33

Research on Chemical Intermediates : Volume 32

Research on Chemical Intermediates : Volume 31

Research on Chemical Intermediates : Volume 30

Research on Chemical Intermediates : Volume 29

Research on Chemical Intermediates : Volume 28

Research on Chemical Intermediates : Volume 27

Research on Chemical Intermediates : Volume 26

Research on Chemical Intermediates : Volume 25

Research on Chemical Intermediates : Volume 24

Research on Chemical Intermediates : Volume 23

Direct photo-oxidation of benzene to phenol over Ti/Si binary oxide prepared by sol-gel method

Content Provider	Springer Nature Link
Author	Ichihashi, Yuichi Taniguchi, Masa Aki Nishiyama, Satoru Tsuruya, Shigeru
Copyright Year	2008
Abstract	Titanium-silicon (Ti/Si) binary oxides having a varying Ti content were prepared using the sol-gel method and used as photocatalysts. The photo-oxidation of benzene to phenol was carried out using Ti/Si binary oxide catalysts in the presence of benzene, water and gaseous oxygen. The amounts of benzene used hardly affected the phenol yield. On the other hand, the addition of sulfuric acid into reaction solution led to the improvement of phenol formation. The H$_{2}$O$_{2}$ formation rate seemed to be related to the phenol yeilds. The photocatalytic reactivity of Ti/Si binary oxide having different TiO$_{2}$ contents was investigated and it was found to be dramatically enhanced in the range of lower TiO$_{2}$ contents. XANES, ESR and XRD spectroscopic investigations of these Ti/Si binary oxide catalysts indicated that Ti species were highly dispersed in SiO$_{2}$ matrices and existed in a tetrahedral coordination. The photo-irradiation of catalysts having tetrahedral Ti species seemed to effectively lead to the formation of H$_{2}$O$_{2}$ as an intermediate.
Starting Page	525
Ending Page	533
Page Count	9
File Format	PDF
ISSN	09226168
Journal	Research on Chemical Intermediates
Volume Number	34
Issue Number	5-7
e-ISSN	15685675
Language	English
Publisher	Springer Netherlands
Publisher Date	2008-01-01
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Ti/Si binary oxide photocatalyst sol-gel method phenol synthesis partial oxidation benzene Catalysis Physical Chemistry Inorganic Chemistry
Content Type	Text
Resource Type	Article
Subject	Chemistry

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

One-Step Oxidation of Benzene to Phenol over Cu/Ti/HZSM-5 Catalysts

Characterization of Ti/Si binary oxides prepared by the sol-gel method and their photocatalytic properties: The hydrogenation and hydrogenolysis of CH$_{3}$CCH with H$_{2}$O

Effect of H$_{2}$O on the partial photo-oxidation of ethylene over Cu/SiO$_{2}$ photocatalyst

Liquid-Phase Oxidation of Benzene to Phenol by Molecular Oxygen over La Catalysts Supported on HZSM-5

Photocatalytic degradation of trichloroethylene using N-doped TiO$_{2}$ prepared by a simple sol–gel process

Supported Pd and PdAu Nanoparticles on Ti-MCM-41 Prepared by a Photo-assisted Deposition Method as Efficient Catalysts for Direct Synthesis of H2O2 from H2 and O2

Photocatalytic Removal of Phenol Under UV Irradiation on WO x –TiO2 Prepared by Sol–Gel Method

Direct Oxidation of Benzene to Phenol Catalyzed by Vanadium Substituted Heteropolymolybdic Acid

Oxidation of benzene to phenol by dioxygen over vanadium oxide nano-plate

Direct photo-oxidation of benzene to phenol over Ti/Si binary oxide prepared by sol-gel method

Similar Documents

One-Step Oxidation of Benzene to Phenol over Cu/Ti/HZSM-5 Catalysts

Characterization of Ti/Si binary oxides prepared by the sol-gel method and their photocatalytic properties: The hydrogenation and hydrogenolysis of CH$_{3}$CCH with H$_{2}$O

Effect of H$_{2}$O on the partial photo-oxidation of ethylene over Cu/SiO$_{2}$ photocatalyst

Liquid-Phase Oxidation of Benzene to Phenol by Molecular Oxygen over La Catalysts Supported on HZSM-5

Photocatalytic degradation of trichloroethylene using N-doped TiO$_{2}$ prepared by a simple sol–gel process

Supported Pd and PdAu Nanoparticles on Ti-MCM-41 Prepared by a Photo-assisted Deposition Method as Efficient Catalysts for Direct Synthesis of H2O2 from H2 and O2

Photocatalytic Removal of Phenol Under UV Irradiation on WO x –TiO2 Prepared by Sol–Gel Method

Direct Oxidation of Benzene to Phenol Catalyzed by Vanadium Substituted Heteropolymolybdic Acid

Oxidation of benzene to phenol by dioxygen over vanadium oxide nano-plate

Direct photo-oxidation of benzene to phenol over Ti/Si binary oxide prepared by sol-gel method