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| Content Provider | Springer Nature Link |
|---|---|
| Author | Baltakys, K. Eisinas, A. Dambrauskas, T. |
| Copyright Year | 2015 |
| Abstract | The influence of aluminum additive on the formation of α-C$_{2}$SH and on kinetics of cementitious binder material at early stages of hydration was determined. α-C$_{2}$SH was synthesized in the primary mixtures with CaO/(SiO$_{2}$ + Al$_{2}$O$_{3}$) = 1.5 and Al$_{2}$O$_{3}$/(SiO$_{2}$ + Al$_{2}$O$_{3}$) = 0; 0.025 and 0.05. The hydrothermal synthesis has been carried out in unstirred suspensions under saturated steam pressure in argon atmosphere at 175 °C temperature for 4, 8;,16, 24, 48 and 72 h by applying extra argon gas (10 bar). It was determined that in CaO–SiO$_{2}$·nH$_{2}$O–H$_{2}$O suspensions within 4 h dicalcium silicate hydrates—α-C$_{2}$S hydrate, C–S–H(II) and a low base semi-crystalline C–S–H(I) type calcium silicate hydrate—were formed. Meanwhile, Al$_{2}$O$_{3}$ additive changes the formation mechanism of synthesis products as well as their stability during the isothermal curing. It was observed that hydrogarnets formed after 4 h of hydrothermal treatment remained stable under all experimental conditions. It was determined that the addition of α-C$_{2}$SH–Al in BM sample changed both the heat flow and the total quantity of heat released during early-stage hydration. It was determined that only 5 % of quartz reacts during the first 4.5 h of hydration in both BM samples, and the further reduction of its quantity depends on duration of process. The products of synthesis and hardening were characterized by simultaneous thermal analysis, microcalorimetry and X-ray diffraction analysis. |
| Starting Page | 75 |
| Ending Page | 84 |
| Page Count | 10 |
| File Format | |
| ISSN | 13886150 |
| Journal | Journal of thermal analysis |
| Volume Number | 121 |
| Issue Number | 1 |
| e-ISSN | 15882926 |
| Language | English |
| Publisher | Springer Netherlands |
| Publisher Date | 2015-03-27 |
| Publisher Place | Dordrecht |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | α-C$_{2}$S hydrate Calcium silicate hydrate (C–S–H) Hydrothermal synthesis Hydration Microcalorimetry Physical Chemistry Analytical Chemistry Polymer Sciences Inorganic Chemistry Measurement Science and Instrumentation |
| Content Type | Text |
| Resource Type | Article |
| Subject | Physical and Theoretical Chemistry Condensed Matter Physics |
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