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| Content Provider | Springer Nature Link |
|---|---|
| Author | Zhao, Houyin Cao, Yan Orndorff, William Pan, Wei Ping |
| Copyright Year | 2014 |
| Abstract | The char gasification characteristics and the composition of evolved gases in a CO$_{2}$ environment have been studied using a thermogravimetric analyzer (TG) coupled with a mass spectrometer. Three types of coal char were studied: lignite (TXL), sub-bituminous (PRB), and bituminous (KYB). TG results showed that the reactivities of TXL and PRB were higher than that of KYB, and the reactivity of TXL was higher than that of PRB. The characterization of the chars implied that the mineral content in the char plays an important role in the reactivity and that the surface area and pore volume may accelerate the reactivity of chars. The evolved gases from three chars were mainly CO and SO$_{2}$. SO$_{2}$ was slightly delayed by CO during gasification of TXL and PRB chars, but for KYB, SO$_{2}$ and CO formed in the same temperature range, but at higher temperatures compared with TXL and PRB. The CO production of KYB was the best, 0.98 mg mg$^{−1}$; and SO$_{2}$ was the least, 0.031 mg mg$^{−1}$. PRB and TXL chars had similar CO production, but SO$_{2}$ in TXL was higher. |
| Starting Page | 1267 |
| Ending Page | 1272 |
| Page Count | 6 |
| File Format | |
| ISSN | 13886150 |
| Journal | Journal of thermal analysis |
| Volume Number | 116 |
| Issue Number | 3 |
| e-ISSN | 15882926 |
| Language | English |
| Publisher | Springer Netherlands |
| Publisher Date | 2014-01-30 |
| Publisher Place | Dordrecht |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Char CO$_{2}$ gasification TG-MS Kinetics Evolved gas Physical Chemistry Analytical Chemistry Polymer Sciences Inorganic Chemistry Measurement Science and Instrumentation |
| Content Type | Text |
| Resource Type | Article |
| Subject | Physical and Theoretical Chemistry Condensed Matter Physics |
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