NDLI: Evaluation of thermal hazard for commercial 14500 lithium-ion batteries

Content Provider	Springer Nature Link
Author	Hsieh, Tsai Ying Duh, Yih Shing Kao, Chen Shan
Copyright Year	2014
Abstract	Commercial lithium-ion batteries ranged from different sizes, shapes, capacities, electrolytes, anode and cathode materials, etc. have recently caused many incidents under abusive or normal operating conditions worldwide. Inherently safer designs with active or passive protections have became the captious issues that need more attentions paid to. In this study, the worst scenarios on thermal runaway of four commercial batteries were conducted and compared. A customized-made closed testing instrument was utilized to measure and track thermal behaviors of four brands of cylindrical lithium-ion batteries under maximum open circuit voltage condition. Characteristics on thermal hazards of lithium-ion batteries such as onset temperature, maximum temperature, maximum self-heat rate, maximum pressures, battery mass loss, etc. were measured and evaluated. Results point out that one brand of cells reached the maximum temperature and maximum self-heat rate of 590.9 K and 1,130.4 K min$^{−1}$, respectively. In conclusion, in case of thermal runaway all the lithium-ion batteries will rupture the cell and catch fire automatically owing to the maximum temperatures over the auto-ignition temperature of electrolytes and the maximum pressure higher than four times of maximum allowable working pressure, respectively. In addition, Lithium-ion battery with cathode material of LiFePO$_{4}$ was verified to be more stable than the lithium-ion battery with cathode material of LiMn$_{2}$O$_{4}$ or LiCoO$_{2}$.
Starting Page	1491
Ending Page	1495
Page Count	5
File Format	PDF
ISSN	13886150
Journal	Journal of thermal analysis
Volume Number	116
Issue Number	3
e-ISSN	15882926
Language	English
Publisher	Springer Netherlands
Publisher Date	2014-04-12
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Lithium-ion battery Cathode material Thermal runaway Physical Chemistry Analytical Chemistry Polymer Sciences Inorganic Chemistry Measurement Science and Instrumentation
Content Type	Text
Resource Type	Article
Subject	Physical and Theoretical Chemistry Condensed Matter Physics

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