NDLI: Preparation and electrical properties of Nd and Mn co-doped Bi$_{4}$Ti$_{3}$O$

Content Provider	Springer Nature Link
Author	Pei, Ling Li, Meiya Liu, Jun Yu, Benfang Wang, Jing Guo, Dongyun Zhao, Xingzhong
Copyright Year	2009
Abstract	Ferroelectric thin films of Nd and Mn co-doped bismuth titanate, Bi$_{3.15}$Nd$_{0.85}$Ti$_{3−x }$Mn$_{x}$O$_{12}$ (BNTM) (x = 0–0.1), were fabricated on Pt/TiO$_{2}$/SiO$_{2}$/Si(100) substrates by a sol–gel technique. The BNTM films had a polycrystalline perovskite structure and uniform and dense surface morphologies. A lattice distortion was observed in the BNTM films due to Mn ion doping. The ferroelectric measurement of the films indicated that the values of coercive field (E $_{c}$) decreased gradually with the increase of the Mn content (x), however, the remanent polarization (P $_{r}$) increase firstly and then decrease with the increase of x. The sample with x = 0.05 had optimum electrical properties and a maximum 2P $_{r}$ value. The 2P $_{r}$ and 2E $_{c}$ values of the film at a maximum applied electric field of 400 kV/cm were 38.3 μC/cm$^{2}$ and 180 kV/cm, respectively. Moreover, this BNTM capacitors did not show fatigue behaviors after 1.0 × 10$^{10}$ switching cycles at a frequency of 1 MHz, suggesting a fatigue-free character. The main reason for the increase of the 2P $_{r}$ and the decrease of the 2E $_{c}$ might be attributed to the lattice distortion in BNTM films due to Mn ion doping.
Starting Page	193
Ending Page	198
Page Count	6
File Format	PDF
ISSN	09280707
Journal	Journal of Sol-Gel Science and Technology
Volume Number	53
Issue Number	2
e-ISSN	15734846
Language	English
Publisher	Springer US
Publisher Date	2009-09-17
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Bi$_{3.15}$Nd$_{0.85}$Ti$_{3−x }$Mn$_{x}$O$_{12}$ Sol–gel technique Ferroelectric polarization Fatigue Nanotechnology Optical and Electronic Materials Inorganic Chemistry Ceramics, Glass, Composites, Natural Methods
Content Type	Text
Resource Type	Article
Subject	Ceramics and Composites Chemistry Materials Chemistry Biomaterials Condensed Matter Physics Electronic, Optical and Magnetic Materials

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