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  1. Journal of Radioanalytical and Nuclear Chemistry
  2. Journal of Radioanalytical and Nuclear Chemistry : Volume 302
  3. Journal of Radioanalytical and Nuclear Chemistry : Volume 302, Issue 1, October 2014
  4. Properties of PAN-TBP extraction chromatographic material
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Journal of Radioanalytical and Nuclear Chemistry : Volume 312
Journal of Radioanalytical and Nuclear Chemistry : Volume 311
Journal of Radioanalytical and Nuclear Chemistry : Volume 310
Journal of Radioanalytical and Nuclear Chemistry : Volume 309
Journal of Radioanalytical and Nuclear Chemistry : Volume 308
Journal of Radioanalytical and Nuclear Chemistry : Volume 307
Journal of Radioanalytical and Nuclear Chemistry : Volume 306
Journal of Radioanalytical and Nuclear Chemistry : Volume 305
Journal of Radioanalytical and Nuclear Chemistry : Volume 304
Journal of Radioanalytical and Nuclear Chemistry : Volume 303
Journal of Radioanalytical and Nuclear Chemistry : Volume 302
Journal of Radioanalytical and Nuclear Chemistry : Volume 302, Issue 3, December 2014
Journal of Radioanalytical and Nuclear Chemistry : Volume 302, Issue 2, November 2014
Journal of Radioanalytical and Nuclear Chemistry : Volume 302, Issue 1, October 2014
In Memoriam Ernest Bujdosó (1932–2014): one of the editors of the Journal of Radioanalytical and Nuclear Chemistry : Remembered by his friend and former colleague Zoltán Szőnyi from the Hungarian Atomic Energy Authority
The effect of the pseudo-colloids in the fractured porous media for safety assessment of a HLW repository: application of arbitrary function
Removal of thorium from aqueous solution by ordered mesoporous carbon CMK-3
Recalibration of U-doped standard glasses through uranium thin film for neutron-fluence measurements
Uranium carbide dissolution in nitric acid: speciation of organic compounds
Radiochemical methodologies applied to determination of zirconium isotopes in low-level waste samples from nuclear power plants
Development of $^{90}$Y-DOTA-nimotuzumab Fab fragment for radioimmunotherapy
Rapid analysis of trinitite with nuclear forensic applications for post-detonation material analyses
Optimization of fundamental parameters in routine production of $^{90}$Y-hydroxyapatite for radiosynovectomy
Adsorption thermodynamic and desorption studies of U(VI) on modified silica gel (SiAPMS-HL)
Transfer factors of $^{40}$K, $^{226}$Ra, $^{232}$Th from soil to different types of local vegetables, radiation hazard indices and their annual doses
Elemental composition and microstructure analysis of a rabbit urolith
Monte Carlo simulation for the evaluation of measurement uncertainty of spent fuel analytical results
Development of a method for the determination of $^{93}$Zr and $^{94}$Nb in radioactive waste using TEVA$^{®}$ resin
Preparation and the biodistribution study of [$^{131}$I]-5,10,15,20-tetrakis(4-hydroxyphenyl)porphyrin and 5-(4-aminophenyl)-10,15,20-triphenylporphyrin
Kinetic study of uranium residue dissolution in ammonium carbonate media
EB-radiolysis of carbamazepine: in pure-water with different ions and in surface water
Impact of mixed low-molecular-weight organic acids on uranium accumulation and distribution in a variant of mustard (Brassica juncea var. tumida)
New EDTA determination method based on ion chromatography with suppressed conductimetric detection
Gamma irradiation induced preparation of poly(acrylamide–itaconic acid)/zirconium hydrous oxide for removal of Cs-134 radionuclide and methylene blue
Formulation and preclinical evaluation of $^{99m}$Tc–gemcitabine as a novel radiopharmaceutical for solid tumor imaging
Measurement of effective atomic number and Rayleigh-to-Compton cross-section ratio for 145 keV gamma photons
Non-uniform polonium distribution in lead–bismuth eutectic revealed by evaporation experiments
Assessment of terrestrial gamma radiation dose rate (TGRD) of Kelantan State, Malaysia: Relationship between the geological formation and soil type to radiation dose rate
Synthesis and biological evaluation of novel $^{99m}$Tc-oxo and $^{99m}$Tc-nitrido complexes with phenylalanine dithiocarbamate for tumor imaging
Mechanism of sorption of pertechnetate onto ordered mesoporous carbon
Radioiodination and biodistribution of isolated lawsone compound from Lawsonia inermis (henna) leaves extract
On the practical aspects of large-scale production of $^{177}$Lu for peptide receptor radionuclide therapy using direct neutron activation of $^{176}$Lu in a medium flux research reactor: the Indian experience
Evaluation of natural gamma radiation and absorbed gamma dose in soil and rocks of Perambalur district (Tamil Nadu, India)
Study on quench effects in liquid scintillation counting during tritium measurements
Generation and bleaching of E′-centers induced in a-SiO$_{2}$ by γ-irradiation
PET imaging of sterile inflammation with a $^{18}$F-labeled bis(zinc(II)-dipicolylamine) complex
Electrochemical behavior of uranyl in ionic liquid 1-butyl-3-methylimidazolium chloride mixture with water
Purification of a $^{166m}$Ho solution by successive high-performance liquid chromatography and gravitational chromatography for half-life determination
Application of alpha particle transport to the modelization of efficiency curves in proportional counters
Sorbent extraction behavior of a nonionic surfactant, Triton X-100, onto commercial charcoal from low level radioactive waste
Radon concentration in drinking water sources of the region adjacent to a tectonically active Karak Thrust, southern Kohat Plateau, Khyber Pakhtunkhwa, Pakistan
Competitive adsorption of uranium(VI) and thorium(IV) ions from aqueous solution using triphosphate-crosslinked magnetic chitosan resins
Properties of PAN-TBP extraction chromatographic material
Synthetic spectra for radioactive strontium production QA/QC
TDCR measurements of $^{3}$H, $^{63}$Ni and $^{55}$Fe using Hidex 300SL LSC device
Radiological mapping in the granodiorite area of Bergama (Pergamon)-Kozak, Turkey
Using the 186-keV peak for $^{226}$Ra activity concentration determination in Hungarian coal-slag samples by gamma-ray spectroscopy
The sequestration of U(VI) on functional β-cyclodextrin-attapulgite nanorods
Magnesium ionophore III as an effective receptor for trivalent europium and americium
Evaluation of chronometers in plutonium age determination for nuclear forensics: What if the ‘Pu/U clocks’ do not match?
High conduction neutron absorber to simulate fast reactor environment in an existing test reactor
Influences of Co-60 gamma-ray irradiation on electrical characteristics of Al$_{2}$O$_{3}$ MOS capacitors
Assessment of inhalation exposure potential of broken uranium ore piles in low-grade uranium mine
Utilization of low-cost sorbent for removal and separation of $^{134}$Cs, $^{60}$Co and $^{152+154}$Eu radionuclides from aqueous solution
Equilibrium and kinetics study of uranium(VI) from aqueous solution by Citrus limetta peels
Determination of difficult-to-measure actinides in evaporator concentrate
Isomeric yield ratios of $^{148}$Pm from the $^{nat}$Sm(γ, x) and the $^{nat}$Nd(p, xn) reactions
Natural radioactivity around former uranium mine, Gabrovnica in Eastern Serbia
The MEDINA facility for the assay of the chemotoxic inventory of radioactive waste packages
Synthesis and Th(IV) sorption characteristics of functionalised graphene oxide
Determination of trace uranyl ions in aquatic medium by a useful and simple method
Major, minor and trace element mass fractions determined using ED-XRF, WD-XRF and INAA for five certified clay reference materials: NCS DC 60102–60105; NCS DC 61101 (GBW 03101A, 03102A, 03103, and 03115)
Adsorption of $^{137}$Cs on titanium ferrocyanide and transformation of the sorbent to lithium titanate: a new method for long term immobilization of $^{137}$Cs
TL characteristics of Ce$^{3+}$-doped NaLi$_{2}$PO$_{4}$ TLD phosphor
Iodine adsorption on silver-exchanged titania-derived adsorbents
Reduced dose uncertainty in MRI-based polymer gel dosimetry using parallel RF transmission with multiple RF sources
Electrodeposition of americium on the stainless steel support for the purpose of radiochemical assay
Phase analysis of the solidified KF–(LiF–NaF–UF$_{4}$)–ZrF$_{4}$ molten electrolytes for the electrowinning of uranium
Radiation-assisted synthesis of iridium and rhodium nanoparticles supported on polyvinylpyrrolidone
Synthesis, characterization and biodistribution of $^{99m}$Tc-Bioquin-HMPAO ($^{99m}$Tc-BH) as a novel brain imaging agent
Extraction equilibrium and thermodynamics of cesium with a new derivative of calix[4]biscrown
Comparative studies on radiolytic degradation of deuterium labeled and unlabeled tributyl phosphates
Constraints on fallout melt glass formation from a near-surface nuclear test
Development of a practical decontamination procedure for uranium-contaminated concrete waste
Simultaneous recovery of plutonium and americium from assorted analytical waste solutions using extraction chromatography
Gold bearing ore assays using $^{197}$Au(γ,n)$^{196}$Au photonuclear reaction
Experimental determination of Q $_{0}$ factors and effective resonance energies with a multi-channel approach: the α-vector method
Transport parameters of I$^{−}$ and IO$_{3}$ $^{−}$ determined in crushed granitic rock columns and groundwater system under dynamic flow conditions
Experimental determination of k $_{0}$, Q $_{0}$ factors, effective resonance energies and neutron cross-sections for 37 isotopes of interest in NAA
Effects of digestion, chemical separation, and deposition on Po-210 quantitative analysis
Investigation of cesium uptake from aqueous solutions using new titanium phosphates ion-exchangers
Development of an ion-exchange method for separation of radioiodine from tellurium and antimony and its application to the production of $^{124}$I via the $^{121}$Sb(α,n)-process
On the lack of capillary Mössbauer spectroscopic effect for Sn$^{II}$-containing aqueous solutions trapped in corning Vycor ‘thirsty’ glass
Parameter optimization and experiment verification for a beta radioluminescence nuclear battery
An electrochemical pathway to prepare circular planar $^{90}$Sr/$^{90}$Y sources for the calibration of surface contamination monitors
Experimental k $_{0}$ and k $_{0}$-fission factors for the determination of the n($^{235}$U)/n($^{238}$U) enrichment levels and correction for $^{235}$U fission interferences in samples containing uranium
First shrinkage parameters of Slovak bentonites considered for engineered barriers in the deep geological repository of high-level radioactive waste and spent nuclear fuel
Letter to the Editor: Comments related to the publication titled “uranium in ground water from Western Haryana, India” by Balvinder Singh, V. K. Garg, Poonam Yadav, Nawal Kishore, Vandana Pulhani, J Radioanal Nucl Chem, DOI 10.1007/s10967-014-3133-y, Published online: 13 April 2014
Authors response to Dr. Rathore’s comments on Singh B, Garg VK, Yadav P, Kishore N, Pulhani V (2014) uranium in groundwater from western Haryana, India. J Radioanal Nucl Chem 301: 427–433
George Hevesy Medal Award 2015: call for nomination and guidelines
Journal of Radioanalytical and Nuclear Chemistry : Volume 301
Journal of Radioanalytical and Nuclear Chemistry : Volume 300
Journal of Radioanalytical and Nuclear Chemistry : Volume 299
Journal of Radioanalytical and Nuclear Chemistry : Volume 298
Journal of Radioanalytical and Nuclear Chemistry : Volume 297
Journal of Radioanalytical and Nuclear Chemistry : Volume 296
Journal of Radioanalytical and Nuclear Chemistry : Volume 295
Journal of Radioanalytical and Nuclear Chemistry : Volume 294
Journal of Radioanalytical and Nuclear Chemistry : Volume 293
Journal of Radioanalytical and Nuclear Chemistry : Volume 292
Journal of Radioanalytical and Nuclear Chemistry : Volume 291
Journal of Radioanalytical and Nuclear Chemistry : Volume 290
Journal of Radioanalytical and Nuclear Chemistry : Volume 289
Journal of Radioanalytical and Nuclear Chemistry : Volume 288
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Journal of Radioanalytical and Nuclear Chemistry : Volume 286
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Journal of Radioanalytical and Nuclear Chemistry : Volume 284
Journal of Radioanalytical and Nuclear Chemistry : Volume 283
Journal of Radioanalytical and Nuclear Chemistry : Volume 282
Journal of Radioanalytical and Nuclear Chemistry : Volume 281
Journal of Radioanalytical and Nuclear Chemistry : Volume 280
Journal of Radioanalytical and Nuclear Chemistry : Volume 279
Journal of Radioanalytical and Nuclear Chemistry : Volume 278
Journal of Radioanalytical and Nuclear Chemistry : Volume 277
Journal of Radioanalytical and Nuclear Chemistry : Volume 276
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Journal of Radioanalytical and Nuclear Chemistry : Volume 252
Journal of Radioanalytical and Nuclear Chemistry : Volume 251
Journal of Radioanalytical and Nuclear Chemistry : Volume 250
Journal of Radioanalytical and Nuclear Chemistry : Volume 249
Journal of Radioanalytical and Nuclear Chemistry : Volume 248
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Journal of Radioanalytical and Nuclear Chemistry : Volume 245
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Journal of Radioanalytical and Nuclear Chemistry : Volume 240
Journal of Radioanalytical and Nuclear Chemistry : Volume 239
Journal of Radioanalytical and Nuclear Chemistry : Volume 238
Journal of Radioanalytical and Nuclear Chemistry : Volume 237
Journal of Radioanalytical and Nuclear Chemistry : Volume 236
Journal of Radioanalytical and Nuclear Chemistry : Volume 235
Journal of Radioanalytical and Nuclear Chemistry : Volume 234
Journal of Radioanalytical and Nuclear Chemistry : Volume 233
Journal of Radioanalytical and Nuclear Chemistry : Volume 232
Journal of Radioanalytical and Nuclear Chemistry : Volume 231
Journal of Radioanalytical and Nuclear Chemistry : Volume 230
Journal of Radioanalytical and Nuclear Chemistry : Volume 229
Journal of Radioanalytical and Nuclear Chemistry : Volume 228
Journal of Radioanalytical and Nuclear Chemistry : Volume 227
Journal of Radioanalytical and Nuclear Chemistry : Volume 226
Journal of Radioanalytical and Nuclear Chemistry : Volume 225
Journal of Radioanalytical and Nuclear Chemistry : Volume 224
Journal of Radioanalytical and Nuclear Chemistry : Volume 223
Journal of Radioanalytical and Nuclear Chemistry : Volume 222
Journal of Radioanalytical and Nuclear Chemistry : Volume 221
Journal of Radioanalytical and Nuclear Chemistry : Volume 220
Journal of Radioanalytical and Nuclear Chemistry : Volume 219
Journal of Radioanalytical and Nuclear Chemistry : Volume 218
Journal of Radioanalytical and Nuclear Chemistry : Volume 217
Journal of Radioanalytical and Nuclear Chemistry : Volume 216
Journal of Radioanalytical and Nuclear Chemistry : Volume 215

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Properties of PAN-TBP extraction chromatographic material

Content Provider Springer Nature Link
Author Mareš, Kamil Vavřinec Šebesta, Ferdinand
Copyright Year 2014
Abstract Three production routes of the preparation of a solid extractant based on tributylphosphate (TBP) embedded in the polyacrylonitrile matrix (PAN) have been studied. The method of direct PAN coagulation with TBP was found to be not viable due to the significant TBP solubility in the coagulation bath. The most suitable PAN-TBP solid extractant was prepared by the well-known impregnation method of ready-made neat PAN beads. The kinetics of uranium extraction from 3 mol L$^{−1}$ HNO$_{3}$, the effect of nitrate and nitric acids concentrations on the value of weight distribution coefficients D $_{g}$ as well as the uranium “extraction isotherm” were determined for this material. Uranium extraction was rather fast, approximately 1 h was sufficient for the equilibrium achievement. Capacity for the uranium uptake, measured in batch experiments on PAN-TBP for 0.048 mol L$^{−1}$ of uranium in 3 mol L$^{−1}$ nitric acid, was found to be q = 0.363 mmol g$^{−1}$ (58 % of the theoretical capacity). It was concluded that PAN-TBP material behaves like TBP in liquid–liquid extraction. Extraction capacity determined in column experiments was lower (by about 23 %) than expected from the “extraction isotherm” due to the TBP leaching out of the column. The thus prepared material is therefore not very suitable for multicycle extraction and stripping and can be used once, particularly for the analytical purposes.
Starting Page 341
Ending Page 345
Page Count 5
File Format PDF
ISSN 02365731
Journal Journal of Radioanalytical and Nuclear Chemistry
Volume Number 302
Issue Number 1
e-ISSN 15882780
Language English
Publisher Springer Netherlands
Publisher Date 2014-07-06
Publisher Place Dordrecht
Access Restriction One Nation One Subscription (ONOS)
Subject Keyword Tributylphosphate TBP Polyacrylonitrile PAN Extraction chromatography Nuclear Chemistry Physical Chemistry Nuclear Physics, Heavy Ions, Hadrons Diagnostic Radiology Inorganic Chemistry
Content Type Text
Resource Type Article
Subject Spectroscopy Pollution Health, Toxicology and Mutagenesis Radiology, Nuclear Medicine and Imaging Analytical Chemistry Public Health, Environmental and Occupational Health Nuclear Energy and Engineering
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