NDLI: Selective synthesis of oligo(carbonate-ether) diols from copolymerization of CO$_{2}$ and propylene oxide under zinc-cobalt double metal cyanide complex

Please wait, while we are loading the content...

Mechanical and thermal properties of coconut shell powder filled polylactic acid biocomposites: effects of the filler content and silane coupling agent

Cyclodextrin-based hyperbranched polymers by acyclic diene metathesis polymerization of an AB$_{n}$ monomer: molecule design, synthesis, and characterization

Polybenzimidazole/poly(tetrafluoro ethylene) composite membranes for high temperature proton exchange membrane fuel cells

Selective synthesis of oligo(carbonate-ether) diols from copolymerization of CO$_{2}$ and propylene oxide under zinc-cobalt double metal cyanide complex

Polychloroprene rubber/ethylene-propylene diene monomer/multiple walled carbon nanotube nanocomposites: synergistic effects of radiation crosslinking and MWNT addition

Network structure and temperature dependence swelling behavior of PEG-b-Poly (NIPAM-co-AMPSA) hydrogels in water

Hydrophilicity and crystallization behavior of PVDF/PMMA/TiO$_{2}$(SiO$_{2}$) composites prepared by in situ polymerization

Study on preparation and properties of novel reactive phenolic hydroxyl-containing polyimides

Effects of dopant, coagulant, and reinforcing nanofiller on mechanical and electrical properties of wet-spun polyaniline nanocomposite fibers

Preparation and characterization of PTFE-g-GMA modified PTFE/SiO$_{2}$ organic–inorganic hybrids

Encapsulation of organomodified montmorillonite with PMMA via in situ SR&NI ATRP in miniemulsion

Characterization of plasticized maize starch/chitosan blends irradiated with an electron beam

Blends of thermoplastic polyurethane (TPU) and polydimethyl siloxane rubber (PDMS), part-I: assessment of compatibility from torque rheometry and mechanical properties

Journal of Polymer Research : Volume 19, Issue 4, April 2012

Journal of Polymer Research : Volume 19, Issue 3, March 2012

Journal of Polymer Research : Volume 19, Issue 2, February 2012

Journal of Polymer Research : Volume 19, Issue 1, January 2012

Journal of Polymer Research : Volume 18

Journal of Polymer Research : Volume 17

Journal of Polymer Research : Volume 16

Journal of Polymer Research : Volume 15

Journal of Polymer Research : Volume 14

Journal of Polymer Research : Volume 13

Journal of Polymer Research : Volume 12

Journal of Polymer Research : Volume 11

Journal of Polymer Research : Volume 10

Journal of Polymer Research : Volume 9

Journal of Polymer Research : Volume 8

Journal of Polymer Research : Volume 7

Journal of Polymer Research : Volume 6

Journal of Polymer Research : Volume 5

Journal of Polymer Research : Volume 4

Selective synthesis of oligo(carbonate-ether) diols from copolymerization of CO$_{2}$ and propylene oxide under zinc-cobalt double metal cyanide complex

Content Provider	Springer Nature Link
Author	Gao, Yonggang Qin, Yusheng Zhao, Xiaojiang Wang, Fosong Wang, Xianhong
Copyright Year	2012
Abstract	Colorless oligo(carbonate-ether) diols were selectively synthesized in high efficiency from copolymerization of CO$_{2}$ and propylene oxide (PO) using Zn$_{3}$[Co(CN)$_{6}$]$_{2}$-based double metal cyanide complex (DMC) as catalyst and different molecular weight polypropylene glycols (PPGs) as chain transfer agent. The catalytic activity was related to carbonate unit content and molecular weight of target oligo(carbonate-ether) diols, for oligo(carbonate-ether) diol with number average molecular weight of 6.4 kg/mol and carbonate unit content of 34.3 %, it reached 10.0 kg oligomer/g DMC catalyst during 10 h of copolymerization. Generally, the number average molecular weight of the oligo(carbonate-ether) diol was tunable between 1.8 kg/mol and 6.4 kg/mol, and the molecular weight distribution was controllable between 1.14 and 1.83. Moreover, the carbonate unit content in the oligo-diols can be adjusted between 15.3 % and 62.5 %, lower temperature and higher CO$_{2}$ pressure were favorable for higher carbonate content. Better selectivity of oligo(carbonate-ether)diol over propylene carbonate(PC) was realized, where the weight ratio of PC (W$_{PC}$) was controlled less than 8.0 wt%. We also found that the alkali metal ion residue may play an important role in PC formation, in some cases this effect may be more significant than backbiting process, removing the residual alkali metal ion should be meaningful in the future to further reduce the PC formation.
Starting Page	1
Ending Page	9
Page Count	9
File Format	PDF
ISSN	10229760
Journal	Journal of Polymer Research
Volume Number	19
Issue Number	5
e-ISSN	15728935
Language	English
Publisher	Springer Netherlands
Publisher Date	2012-04-25
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Carbon dioxide Propylene oxide Double metal cyanide complex catalyst Oligo(carbonate-ether) diols Industrial Chemistry/Chemical Engineering Polymer Sciences Characterization and Evaluation of Materials
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Materials Chemistry Polymers and Plastics

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Co-Ni Cyanide Bi-Metal Catalysts: Copolymerization of Carbon Dioxide with Propylene Oxide and Chain Transfer Agents

Copolymerization of $CO_{2}$, propylene oxide, and itaconic anhydride with double metal cyanide complex catalyst to form crosslinked polypropylene carbonate

Novel ternary block copolymerization of carbon dioxide with cyclohexene oxide and propylene oxide using zinc complex catalyst

Alternating copolymerization of cyclohexene oxide and carbon dioxide under cobalt porphyrin catalyst

Effect of electron density on the catalysts for copolymerization of propylene oxide and CO$_{2}$

Copolymerization of carbon dioxide and propylene oxide using an aluminum porphyrin system and its components

DMC-Mediated Copolymerization of $CO_{2}$ and PO—Mechanistic Aspects Derived from Feed and Polymer Composition

Synthesis and characterization of high molecular weight poly(1,2-propylene carbonate-co-1,2-cyclohexylene carbonate) using zinc complex catalyst

Silica-supported zinc glutarate catalyst synthesized by rheological phase reaction used in the copolymerization of carbon dioxide and propylene oxide

Selective synthesis of oligo(carbonate-ether) diols from copolymerization of CO$_{2}$ and propylene oxide under zinc-cobalt double metal cyanide complex

Similar Documents

Co-Ni Cyanide Bi-Metal Catalysts: Copolymerization of Carbon Dioxide with Propylene Oxide and Chain Transfer Agents

Copolymerization of $CO_{2}$, propylene oxide, and itaconic anhydride with double metal cyanide complex catalyst to form crosslinked polypropylene carbonate

Novel ternary block copolymerization of carbon dioxide with cyclohexene oxide and propylene oxide using zinc complex catalyst

Alternating copolymerization of cyclohexene oxide and carbon dioxide under cobalt porphyrin catalyst

Effect of electron density on the catalysts for copolymerization of propylene oxide and CO$_{2}$

Copolymerization of carbon dioxide and propylene oxide using an aluminum porphyrin system and its components

DMC-Mediated Copolymerization of $CO_{2}$ and PO—Mechanistic Aspects Derived from Feed and Polymer Composition

Synthesis and characterization of high molecular weight poly(1,2-propylene carbonate-co-1,2-cyclohexylene carbonate) using zinc complex catalyst

Silica-supported zinc glutarate catalyst synthesized by rheological phase reaction used in the copolymerization of carbon dioxide and propylene oxide

Selective synthesis of oligo(carbonate-ether) diols from copolymerization of CO$_{2}$ and propylene oxide under zinc-cobalt double metal cyanide complex