NDLI: Measurements and Calculations of the Solid–Liquid Equilibria in the Quaternary Systems NaBr–KBr–MgBr$_{2}$–H$_{2}$O and NaBr–KBr–CaBr$_{2}$–H$

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Measurements and Calculations of the Solid–Liquid Equilibria in the Quaternary Systems NaBr–KBr–MgBr$_{2}$–H$_{2}$O and NaBr–KBr–CaBr$_{2}$–H$_{2}$O at 348.15 K

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Measurements and Calculations of the Solid–Liquid Equilibria in the Quaternary Systems NaBr–KBr–MgBr$_{2}$–H$_{2}$O and NaBr–KBr–CaBr$_{2}$–H$_{2}$O at 348.15 K

Content Provider	Springer Nature Link
Author	Hu, Juanxin Sang, Shihua Liu, Qingzhu
Copyright Year	2015
Abstract	Solid–liquid equilibria in the quaternary systems NaBr–KBr–MgBr$_{2}$–H$_{2}$O and KBr–NaBr–CaBr$_{2}$–H$_{2}$O at 348.15 K were determined using the method of isothermal solution saturation. The solubilities of the equilibrium solutions were determined. According to the experimental data, the equilibrium phase diagrams and water content diagrams of the two quaternary systems were plotted. The solubility diagram of the quaternary NaBr–KBr–MgBr$_{2}$–H$_{2}$O system has two invariant points, five univariant curves, and four crystallization fields (which are saturated with MgBr$_{2}$·6H$_{2}$O, KBr·MgBr$_{2}$·6H$_{2}$O, NaBr and KBr, respectively, where KBr·MgBr$_{2}$·6H$_{2}$O is a double salt). The solubility diagram of the quaternary system KBr–NaBr–CaBr$_{2}$–H$_{2}$O includes one invariant point, three univariant curves, and three crystallization fields (CaBr$_{2}$·2H$_{2}$O, KBr and NaBr). The dissolution equilibrium constant K of NaBr, KBr, MgBr$_{2}$·6H$_{2}$O, KBr·MgBr$_{2}$·6H$_{2}$O and CaBr$_{2}$·2H$_{2}$O at 348.15 K were fitted using Pitzer’s equation. A chemical model based on the Pitzer equation was constructed to calculate the solubilities of salts in the two quaternary systems at 348.15 K. The calculated solubilities are in agreement with experimental results.
Starting Page	1963
Ending Page	1975
Page Count	13
File Format	PDF
ISSN	00959782
Journal	Journal of Solution Chemistry
Volume Number	44
Issue Number	10
e-ISSN	15728927
Language	English
Publisher	Springer US
Publisher Date	2015-10-01
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Solid–liquid equilibrium Pitzer model Solubility Bromide salts Physical Chemistry Industrial Chemistry/Chemical Engineering Geochemistry Oceanography Inorganic Chemistry Condensed Matter Physics
Content Type	Text
Resource Type	Article
Subject	Biochemistry Molecular Biology Biophysics Physical and Theoretical Chemistry

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Measurements and Calculations of Solid–Liquid Equilibria in the Ternary System NaCl–NaBr–H$_{2}$O at 323 K

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Measurements of the Solid–Liquid Equilibria in the Quaternary System NaCl–NaBr–Na$_{2}$SO$_{4}$–H$_{2}$O at 323 K

Study of Phase Equilibrium of NaBr + KBr + H 2 O and NaBr + MgBr 2 + H 2 O at 313 . 15

Measurement and thermodynamic model study on equilibrium solubility in the ternary system KCl-KBr-H$_{2}$O at 323.15 K

Solid-liquid equilibria in the quaternary system Na$^{+}$, K$^{+}$//Br$^{−}$, B$_{4}$O$_{7}$ $^{2−}$-H$_{2}$O at 298 K

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Measurements and Calculations of the Solid–Liquid Equilibria in the Quaternary Systems NaBr–KBr–MgBr$_{2}$–H$_{2}$O and NaBr–KBr–CaBr$_{2}$–H$_{2}$O at 348.15 K

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