NDLI: Liquid-solid metastable phase equilibria for the quaternary system (NaCl-KCl-CaCl$_{2}$-H$

Content Provider	Springer Nature Link
Author	Li, D. C. Deng, T. L.
Copyright Year	2009
Abstract	The solubility and the physicochemical properties (densities, viscosities, refractive indices, conductivities and pH) in the liquid-solid metastable system (NaCl-KCl-CaCl$_{2}$-H$_{2}$O) at 308.15 K have been investigated using the isothermal evaporation method, and the dry-salt phase diagram, water-phase diagram, and the diagram of physicochemical properties vs. composition in the system were plotted. One three-salt cosaturated point, three metastable solubility isotherm curves, and three crystallization regions corresponding to sodium chloride, potassium chloride and calcium chloride tetrahydrate were formed, and neither solid solution nor double salts were found. On the basis of the extended Harvie-Weare (HW) model and its temperature-dependent equation, the values of the Pitzer parameters β$^{(0)}$, β$^{(1)}$, C $^{ϕ}$ for NaCl, KCl and CaCl$_{2}$, the mixing ion-interaction parameters θ$_{Na,K}$, θ$_{Na,Ca}$, θ$_{K,Ca}$, Ψ$_{Na,K,Cl}$, Ψ$_{Na,Ca,Cl}$, Ψ$_{K,Ca,Cl}$, and the Debye-Hückel parameter A $^{ϕ}$ and the chemical potentials of the minerals in the quaternary system at 308.15 K were fitted, and the predictive solubility based on the temperature-dependent equation and the chemical potentials of the minerals agrees well with the experimental data.
Starting Page	361
Ending Page	367
Page Count	7
File Format	PDF
ISSN	13886150
Journal	Journal of thermal analysis
Volume Number	95
Issue Number	2
e-ISSN	15728943
Language	English
Publisher	Springer Netherlands
Publisher Date	2009-03-12
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	metastable phase equilibrium Pitzer parameters solubility Measurement Science, Instrumentation Inorganic Chemistry Polymer Sciences Analytical Chemistry Physical Chemistry
Content Type	Text
Resource Type	Article
Subject	Physical and Theoretical Chemistry Condensed Matter Physics

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Metastable phase equilibria in the systems K$_{2}$SO$_{4}$ + K$_{2}$B$_{4}$O$_{7}$ + H$_{2}$O and KCl + K$_{2}$B$_{4}$O$_{7}$ + H$_{2}$O at 308.15 K

Solubilities of salts in the ternary systems NaCl + CaCl$_{2}$ + H$_{2}$O and KCl + CaCl$_{2}$ + H$_{2}$O at 75°C

Simulation studies on metastable phase equilibria in the aqueous ternary systems (NaCl-MgCl$_{2}$-H$_{2}$O) and (KCl-MgCl$_{2}$-H$_{2}$O) at 308.15 K

Solid–liquid equilibria in the NaCl–SrCl$_{2}$–H$_{2}$O system at 288.15 K

Solid and liquid metastable phase equilibria in the aqueous quaternary system Li$^{+}$, Mg$^{2+}$//SO$_{4}$ $^{2–}$, borate-H$_{2}$O at 273.15 K

Solid-liquid phase equilibria at 50 and 75°C in the NaCl + MgCl$_{2}$ + H$_{2}$O system and the pitzer model representations

Equilibria in the ternary system SrCl$_{2}$-KCl-H$_{2}$O and the quaternary system SrCl$_{2}$-KCl-NaCl-H$_{2}$O at 323 K

Phase equilibria of quaternary system NaCl-NaBr-Na$_{2}$B$_{4}$O$_{7}$-H$_{2}$O at 348 K

Metastable phase equilibria for the ternary aqueous system of lithium sulfate and potassium sulfate at T = 308.15 K: Experimental data and prediction using Pitzer model

Liquid-solid metastable phase equilibria for the quaternary system (NaCl-KCl-CaCl$_{2}$-H$_{2}$O) at 308.15 K

Similar Documents

Metastable phase equilibria in the systems K$_{2}$SO$_{4}$ + K$_{2}$B$_{4}$O$_{7}$ + H$_{2}$O and KCl + K$_{2}$B$_{4}$O$_{7}$ + H$_{2}$O at 308.15 K

Solubilities of salts in the ternary systems NaCl + CaCl$_{2}$ + H$_{2}$O and KCl + CaCl$_{2}$ + H$_{2}$O at 75°C

Simulation studies on metastable phase equilibria in the aqueous ternary systems (NaCl-MgCl$_{2}$-H$_{2}$O) and (KCl-MgCl$_{2}$-H$_{2}$O) at 308.15 K

Solid–liquid equilibria in the NaCl–SrCl$_{2}$–H$_{2}$O system at 288.15 K

Solid and liquid metastable phase equilibria in the aqueous quaternary system Li$^{+}$, Mg$^{2+}$//SO$_{4}$ $^{2–}$, borate-H$_{2}$O at 273.15 K

Solid-liquid phase equilibria at 50 and 75°C in the NaCl + MgCl$_{2}$ + H$_{2}$O system and the pitzer model representations

Equilibria in the ternary system SrCl$_{2}$-KCl-H$_{2}$O and the quaternary system SrCl$_{2}$-KCl-NaCl-H$_{2}$O at 323 K

Phase equilibria of quaternary system NaCl-NaBr-Na$_{2}$B$_{4}$O$_{7}$-H$_{2}$O at 348 K

Metastable phase equilibria for the ternary aqueous system of lithium sulfate and potassium sulfate at T = 308.15 K: Experimental data and prediction using Pitzer model

Liquid-solid metastable phase equilibria for the quaternary system (NaCl-KCl-CaCl$_{2}$-H$_{2}$O) at 308.15 K