NDLI: Effect of Nitrile-Functionalization of Imidazolium-Based Ionic Liquids on Their Transport Properties, Both Pure and Mixed with Lithium Salts

Content Provider	Springer Nature Link
Author	Srour, Hassan Traïkia, Mounir Fenet, Bernard Rouault, Hélène Costa Gomes, Margarida F. Santini, Catherine C. Husson, Pascale
Copyright Year	2014
Abstract	The influence of the presence of a nitrile group in the cation of imidazolium-based ionic liquids on their transport properties was investigated. As these liquids can be used as electrolytes in lithium ion batteries, their mixtures with lithium salts were also considered. 1-Butyl-3-methylimidazolium bis(trifluoromethylsulphonyl)imide, [C$_{1}$C$_{4}$Im][NTf$_{2}$], 1-butylnitril-3-methylimidazolium bis(trifluoromethylsulphonyl)imide, [C$_{1}$C$_{3}$CNIm][NTf$_{2}$], and their mixtures with bis(trifluoromethylsulphonyl)imide lithium, Li[NTf$_{2}$], were studied. Their mass transport properties (viscosity, ionic conductivity, self-diffusion) were experimentally determined. NMR spectroscopy was also used to explore molecular organization and interactions in these systems. The addition of a cyano group increases the viscosity and the ionicity of the liquid. The effect of lithium ion is more pronounced on [C$_{1}$C$_{3}$CNIm][NTf$_{2}$], with interactions between Li$^{+}$ and the nitrile group.
Starting Page	495
Ending Page	510
Page Count	16
File Format	PDF
ISSN	00959782
Journal	Journal of Solution Chemistry
Volume Number	44
Issue Number	3-4
e-ISSN	15728927
Language	English
Publisher	Springer US
Publisher Date	2014-12-23
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Viscosity Conductivity Diffusion Ionicity NMR spectroscopy Lithium Nitrile-functionalization Ionic liquids Physical Chemistry Industrial Chemistry/Chemical Engineering Geochemistry Oceanography Inorganic Chemistry Condensed Matter Physics
Content Type	Text
Resource Type	Article
Subject	Biochemistry Molecular Biology Biophysics Physical and Theoretical Chemistry

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