NDLI: Composition and Temperature Dependence of Excess Properties of Binary Mixtures of Imidazolium Based Ionic Liquids: II ([C$_{ n }$mim][PF$

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Composition and Temperature Dependence of Excess Properties of Binary Mixtures of Imidazolium Based Ionic Liquids: II ([C$_{ n }$mim][PF$_{6}$]) + Propylamine

Content Provider	Springer Nature Link
Author	Vaid, Zuber More, Utkarsh U. Gardas, Ramesh L. Malek, Naved I. Ijardar, Sushma P.
Copyright Year	2015
Abstract	The experimental data of densities, ρ, speeds of sound, u, and refractive indices, $$ n_{\text{D}} $$ , for pure ionic liquids, 1-butyl-3-methylimidazolium hexafluorophosphate ([C$_{4}$mim][PF$_{6}$]), 1-hexyl-3-methylimidazolium hexafluorophosphate ([C$_{6}$mim][PF$_{6}$]) and 1-octyl-3-methylimidazolium hexafluorophosphate ([C$_{8}$mim][PF$_{6}$]) and their binary mixtures with propylamine were measured by an Anton Paar DSA 5000 densimeter and Abbemat 300 refractometer, respectively. The measurements were performed as a function of concentration and at temperatures between 293.15 and 313.15 K and at 0.1 MPa. From these measured values, the excess molar volumes $$ V_{\text{m}}^{\text{E}} $$ , excess molar isentropic compressibilities $$ K_{S,\text{m}}^{\text{E}} $$ , and refractive index deviations $$ \Delta_{\varphi } n_{\text{D}} $$ were derived and correlated with the Redlich–Kister polynomial equation. The values of $$ V_{\text{m}}^{\text{E}} $$ and $$ K_{S,\text{m}}^{\text{E}} $$ are negative and decrease with increase in temperature whereas the $$ \Delta_{\varphi } n_{\text{D}} $$ are positive and increase with temperature for all studied systems. $$ V_{\text{m}}^{\text{E}} $$ and $$ K_{S,\text{m}}^{\text{E}} $$ decrease with increasing alkyl chain length of ILs. The variations in excess properties are discussed with respect to increases in temperature, addition of –CH$_{2}$ groups in alkyl chain of ILs and the strength of solute-solvent interactions existing in the ILs + amine mixtures. $$ V_{\text{m}}^{\text{E}} $$ was also predicted from the Prigogine–Flory–Patterson theory.
Starting Page	718
Ending Page	741
Page Count	24
File Format	PDF
ISSN	00959782
Journal	Journal of Solution Chemistry
Volume Number	44
Issue Number	3-4
e-ISSN	15728927
Language	English
Publisher	Springer US
Publisher Date	2015-04-01
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Ionic liquid Excess molar volume Excess molar isentropic compressibility Refractive index deviation Prigogine–Flory–Patterson theory Physical Chemistry Industrial Chemistry/Chemical Engineering Geochemistry Oceanography Inorganic Chemistry Condensed Matter Physics
Content Type	Text
Resource Type	Article
Subject	Biochemistry Molecular Biology Biophysics Physical and Theoretical Chemistry

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Composition and Temperature Dependence of Excess Properties of Binary Mixtures of Imidazolium Based Ionic Liquids: II ([C$_{ n }$mim][PF$_{6}$]) + Propylamine

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Composition and Temperature Dependence of Excess Properties of Binary Mixtures of Imidazolium Based Ionic Liquids: II ([C$_{ n }$mim][PF$_{6}$]) + Propylamine