NDLI: Red-Shift Index Concept in Solvent Effects of Chromophore-Substituted Metallophthalocyanines: A Look at the Empirical Relationship of the Macroscopic Properties of the Solute

Content Provider	Springer Nature Link
Author	Akpe, Victor Ogunsipe, Abimbola Madu, Christian Brismar, Hjalmar
Copyright Year	2015
Abstract	Solvent effects on the UV/vis spectra of metallopthalocyanines (MPcs) have been interpreted using the red-shift index concept (R $_{ s }$ I). The concept connects empirically, direct, experimental, easily accessible optical spectral data, which are explained by considering the differential behavior of the solute–solvent interactions at the ground state and excited state using the spectral values of MPcs along with the derived concept, called the associated solvation energy (ASE). R $_{ s }$ I is formulated from three fundamental parameters, which are: ground state electronic absorption spectrum, polarization red-shift and a scaling factor of MPc (N $_{dye}$) in the respective solvents. The R $_{ s }$ I is a reflection of the index value of the chromophore substituent of MPc in the solvent; thus, the concept can be used as a solvatochromic parameter to study a wide range of supramolecular and heterocyclic compounds that can be modified at their periphery or ‘handles’. Particularly, in this study, the concept has been used to rank MPc candidates by using the statistical mean performance of the solvatochromic parameters, which are red shift index, polarizability efficiency and ASE. We hereby review the solvent effects on the UV/vis spectra of substituted and unsubstituted MPcs.
Starting Page	307
Ending Page	326
Page Count	20
File Format	PDF
ISSN	00959782
Journal	Journal of Solution Chemistry
Volume Number	44
Issue Number	2
e-ISSN	15728927
Language	English
Publisher	Springer US
Publisher Date	2015-02-22
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Aggregation behavior Solvation Polarization red-shift Solvent polarity Metallophthalocyanine Physical Chemistry Industrial Chemistry/Chemical Engineering Geochemistry Oceanography Inorganic Chemistry Condensed Matter Physics
Content Type	Text
Resource Type	Article
Subject	Biochemistry Molecular Biology Biophysics Physical and Theoretical Chemistry

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Solvatochromism and Preferential Solvation of 4-Pentacyanoferrate 4′-Aryl Substituted Bipyridinium Complexes in Binary Mixtures of Hydroxylic and Non-hydroxylic Solvents

Molecular-Microscopic Properties and Preferential Solvation in Protic Ionic Liquid Mixtures

Spectral Investigations of Preferential Solvation and Solute–Solvent Interactions of Free Base and Protonated 5,10,15,20-Tetrakis(4-trimethyl-ammonio-phenyl)-porphine Tetratosylate in Aqueous Organic Mixed Solvents

Thermodynamic Studies of Ionic Interactions for the Drug Ranitidine Hydrochloride in Aqueous Solutions at 298.15 K

Solute–Solvent Interaction Effects on Protonation and Aggregation Constants of TTMAPP in Different Aqueous Solutions of Methanol

Solvation and Solvatochromism: An Overview

Effects of Volume-% of Voids in a Solvent and Repulsive Solute–Solvent Interactions, on Limiting Partial Molar Volumes (V $^{∞}$) in Solvent (1)–Solute (2) Systems

Solute-Solvent Interactions in Solutions of Solvatochromic Phenoxides: A Dynamics Simulation Study

The Solvation of Anions in Propylene Carbonate

Red-Shift Index Concept in Solvent Effects of Chromophore-Substituted Metallophthalocyanines: A Look at the Empirical Relationship of the Macroscopic Properties of the Solute–Solvent Interactions

Similar Documents

Solvatochromism and Preferential Solvation of 4-Pentacyanoferrate 4′-Aryl Substituted Bipyridinium Complexes in Binary Mixtures of Hydroxylic and Non-hydroxylic Solvents

Molecular-Microscopic Properties and Preferential Solvation in Protic Ionic Liquid Mixtures

Spectral Investigations of Preferential Solvation and Solute–Solvent Interactions of Free Base and Protonated 5,10,15,20-Tetrakis(4-trimethyl-ammonio-phenyl)-porphine Tetratosylate in Aqueous Organic Mixed Solvents

Thermodynamic Studies of Ionic Interactions for the Drug Ranitidine Hydrochloride in Aqueous Solutions at 298.15 K

Solute–Solvent Interaction Effects on Protonation and Aggregation Constants of TTMAPP in Different Aqueous Solutions of Methanol

Solvation and Solvatochromism: An Overview

Effects of Volume-% of Voids in a Solvent and Repulsive Solute–Solvent Interactions, on Limiting Partial Molar Volumes (V $^{∞}$) in Solvent (1)–Solute (2) Systems

Solute-Solvent Interactions in Solutions of Solvatochromic Phenoxides: A Dynamics Simulation Study

The Solvation of Anions in Propylene Carbonate

Red-Shift Index Concept in Solvent Effects of Chromophore-Substituted Metallophthalocyanines: A Look at the Empirical Relationship of the Macroscopic Properties of the Solute–Solvent Interactions