NDLI: Catalysis Application of Metal (Rh, Ir) Quinonoid Complexes

Content Provider	Springer Nature Link
Author	Kim, Sang Bok
Copyright Year	2013
Abstract	Many metal quinonoid complexes have been synthesized and studied due to their interesting properties. Quinonoid molecules can participate in proton-coupled inter-molecular redox reactions. By combining metals with quinonoid molecules, the resulting π-bonded metal complexes can experience proton-coupled intra-molecular redox process between metal and quinonoid molecules. As a result of these intra-molecular redox reactions, positive, neutral, and anionic π-bonded quinonoid metal complexes are reversibly formed and are isolated with relative ease. Many applications of metal quinonoid complexes have been studied relevant to coordination networks, nano-chemistry, surface chemistry, anti-cancer agents, and luminescent materials. Catalysis applications of metal quinonoid complexes had not been shown before 2005. New catalytic applications of π-bonded quinonoid rhodium complex are reviewed. In addition, both homogeneous and heterogeneous catalyses by metal (Rh, Ir) quinonoid complex are discussed.
Starting Page	58
Ending Page	65
Page Count	8
File Format	PDF
ISSN	15741443
Journal	Journal of Inorganic and Organometallic Polymers and Materials
Volume Number	24
Issue Number	1
e-ISSN	15741451
Language	English
Publisher	Springer US
Publisher Date	2013-10-20
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	π-Bonded quinonoid metal complex Catalysis Coordination polymer Inorganic Chemistry Organic Chemistry Polymer Sciences
Content Type	Text
Resource Type	Article
Subject	Materials Chemistry Polymers and Plastics

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