NDLI: Synthesis, Structures of Salen-Type 3d–4f Heteronuclear Metal Complexes

Content Provider	Springer Nature Link
Author	Liu, Fei Zhang, Qian Hou, Guangfeng Chen, Qifan Chen, Peng Li, Guangming
Copyright Year	2013
Abstract	Three new salen-type 3d–4f heteronuclear metal complexes incorporating with the semi-rigid ligand N,N′-bis(2-hydroxy-3-methoxybenzylidene)-1,2-diaminocyclohexane (H$_{2}$L), namely, [(CuClL)LaCl$_{2}$(CH$_{3}$OH)$_{3}$]·H$_{2}$O (1), [(CuClL)DyCl$_{2}$(CH$_{3}$OH)$_{2}$] (2) and [(CuClL)$_{2}$GdCl$_{2}$(CH$_{3}$OH)$_{2}$] (3), have been isolated. X-ray crystallographic analysis indicates that 1 and 2 possess the typical heterodinuclear structures, while, complex 3 has a trinuclear structure. In 1–3, the Cu$^{2+}$ ion is in the N$_{2}$O$_{2}$ cavity of the ligand and the lanthanide ions are to the O$_{2}$O$_{2}$ set of the ligand. The coordination numbers of the lanthanide ions are reduced from 9 to 8 along with lanthanide contraction. These results further enrich the structures of salen type 3d–4f heteronuclear complexes.Pictogram
Starting Page	1097
Ending Page	1103
Page Count	7
File Format	PDF
ISSN	15741443
Journal	Journal of Inorganic and Organometallic Polymers and Materials
Volume Number	23
Issue Number	5
e-ISSN	15741451
Language	English
Publisher	Springer US
Publisher Date	2013-06-26
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Synthesis Structure Salen-type 3d–4f Heteronuclear metal complexes Inorganic Chemistry Organic Chemistry Polymer Sciences
Content Type	Text
Resource Type	Article
Subject	Materials Chemistry Polymers and Plastics

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