NDLI: Immobilization of Metalloporphyrin on Functionalized MCM-48 Nanoporous Silica as a Catalyst in Oxidation of Cyclohexene: The Effects of Nanoporous Structure of MCM-48 on Its Catalytic Efficiency

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Immobilization of Metalloporphyrin on Functionalized MCM-48 Nanoporous Silica as a Catalyst in Oxidation of Cyclohexene: The Effects of Nanoporous Structure of MCM-48 on Its Catalytic Efficiency

Content Provider	Springer Nature Link
Author	Sabour, Behrouz Mehrani, Kheirollah Mehrani, Azadeh Peyrovi, Mohammad Hassan
Copyright Year	2013
Abstract	MCM-48 nanoporous silica were prepared by the sol–gel method and functionalized by pyridine using a silane agent. With the aid of pyridines on the surface, the nanoporous material was used as a support for immobilization of metalloporphyrin. The formation of this material was confirmed by infrared spectroscopy, X-ray powder diffraction, transmission electron microscopy, inductively coupled plasma atomic emission spectroscopy analysis and specific surface area measurement. The application of this metalloporphyrin-immobilized MCM-48 was investigated as a heterogeneous catalyst in cyclohexene oxidation. Various parameters such as solvent and time were optimized. Also the effect of nanoporous structure on the efficiency of the catalyst was investigated by comparing the results with the same composite using nonporous silica (SiO$_{2}$). The result showed that the MCM-48 immobilized metalloporphyrin is a better catalyst for cyclohexene oxidation, which can be attributed to its nanoporous structure. The nanoporous structure increases the surface area of MCM-48 and leads to more metalloporphyrin immobilization.
Starting Page	1183
Ending Page	1188
Page Count	6
File Format	PDF
ISSN	15741443
Journal	Journal of Inorganic and Organometallic Polymers and Materials
Volume Number	23
Issue Number	5
e-ISSN	15741451
Language	English
Publisher	Springer US
Publisher Date	2013-06-07
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Functionalized MCM-48 Nanoporous structure Metalloporphyrin Cyclohexene oxidation Inorganic Chemistry Organic Chemistry Polymer Sciences
Content Type	Text
Resource Type	Article
Subject	Materials Chemistry Polymers and Plastics

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