NDLI: Syntheses and Crystal Structures of Two Ferrocenyl Dicarboximides

Content Provider	Springer Nature Link
Author	Zhu, Bei Bei Shi, Yao Cheng Li, Qian Kun
Copyright Year	2011
Abstract	Reactions of 1,1′-ferrocenedicarboxylic chloride with 2-aminopyrimidine and 2-aminopyrazine produce organometallic dicarboximides I and II, respectively. They crystallize in space groups F dd2 and P2$_{1}$/c, respectively. The molecules of I lying on twofold rotation axes are linked into a B-faced sheet by a C–H···O=C hydrogen bond [H····O = 2.46, C···O = 3.163(7) Å and C–H···O = 132°]. The sheets are linked into a layered structure by two types of weak C–H···O=C hydrogen bonds [H···O = 2.71, C···O = 3.340(8) Å and C–H···O = 126°; H···O = 2.69, C···O = 3.303(10) Å and C–H···O = 124°]. The molecules of II are linked into a centrosymmetric R 2 2 (12) dimer by a C–H···O hydrogen bond [H···O = 2.40, C···O = 3.321(10) Å and C–H···O = 172°]. The dimers are further packed along the a axis by a C–H···O hydrogen bond [H···O = 2.69, C···O = 3.416(9) Å and C–H···O = 135°] to give an [100] double-chain. The double-chain is packed in the [010] direction by a C–H···O=C hydrogen bond [H···O = 2.69, C···O = 3.532(9) Å and C–H···O = 150°]. Further the intermolecular C–H···N hydrogen bond involving the cyclopentadienyl group as a hydrogen-bond donor and pyrazine N atom as an acceptor [H···O = 2.71, C···N = 3.536(10) Å and C–H···N = 148°] leads to a three-dimensional framework structure.Reactions of 1,1′-ferrocenedicarboxyl chloride with 2-aminopyrimidine and 2-aminopyrazine yielded two bent dicarboximides Fe(C$_{5}$H$_{4}$CO)$_{2}$NAr [I, Ar = 2-C$_{4}$H$_{3}$N$_{2}$, 2-pyrimidyl; II, Ar = 2-C$_{4}$H$_{3}$N$_{2}$, 2-pyrazinyl].
Starting Page	1
Ending Page	6
Page Count	6
File Format	PDF
ISSN	10741542
Journal	Journal of Chemical Crystallography
Volume Number	42
Issue Number	1
e-ISSN	15728854
Language	English
Publisher	Springer US
Publisher Date	2011-11-09
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	1,1′-Ferrocenedicarboxylic acid 1,1′-Ferrocenedicarboxylic chloride Dicarboximide Bent ferrocene X-ray crystallography Inorganic Chemistry Organometallic Chemistry Physical Chemistry Crystallography
Content Type	Text
Resource Type	Article
Subject	Chemistry Condensed Matter Physics

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