NDLI: Ring Puckering in Chloride-[N,N′-Bis(2,6-Diisopropylphenyl)-2,2,6,6-Tetramethylheptane-3,5-Diiminato]Tin(II)

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Ring Puckering in Chloride-[N,N′-Bis(2,6-Diisopropylphenyl)-2,2,6,6-Tetramethylheptane-3,5-Diiminato]Tin(II)

Content Provider	Springer Nature Link
Author	Muñoz Flores, Blanca M. Jiménez Pérez, Víctor M. Santillan, Rosa Hernández Fernández, Eugenio López Cortina, Susana Kharisov, Boris I.
Copyright Year	2011
Abstract	Reaction of the β-diketiminato lithium salt {CH[(C$^{t}$Bu)(2,6-$^{i}$Pr$_{2}$C$_{6}$H$_{3}$N)]$_{2}$}$^{−}$Li$^{+}$ with SnCl$_{2}$ provided the derivative {CH[(C$^{t}$Bu)(2,6-$^{i}$Pr$_{2}$C$_{6}$H$_{3}$N)$_{2}$}SnCl with a three-coordinate tin(II) ion. The crystal structure shows a non-planar ligand skeleton and a tin(II) ion with a distorted tetrahedral pyramidal geometry with one vertex occupied by an unshared electron pair. The Sn(II) ion out of the N2–C3–C2–C1–N1 plane (Φ-length) is 0.674 Å because of the steric hindrance between the tert-butyl groups and the N-aryl groups. The Sn–N1 [2.224 (19) Å] and Sn–N2 [2.1423 (18) Å] distances in the heterocycle corresponded with a delocalized system, while the most acute angle was associated with the bite of the chelating ligand N–Sn–N 87.94 (7)°.Here we report the crystal structure of tin(II) ion bearing a β-diketiminato ligand as well as the influence of α-carbon bulky substituent on the ring puckering.
Starting Page	34
Ending Page	37
Page Count	4
File Format	PDF
ISSN	10741542
Journal	Journal of Chemical Crystallography
Volume Number	42
Issue Number	1
e-ISSN	15728854
Language	English
Publisher	Springer US
Publisher Date	2011-10-28
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Tin(II) ion Carbene analog Ring puckering X-ray diffraction study Inorganic Chemistry Organometallic Chemistry Physical Chemistry Crystallography
Content Type	Text
Resource Type	Article
Subject	Chemistry Condensed Matter Physics

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Erratum to: 2,4-Pentane N,N′-Bis(2,6-Diisopropylphenyl) ketiminato cobalt (II) (trimethylsilyl)methylene

2,4-Pentane N,N′-Bis(2,6-Diisopropylphenyl) ketiminato cobalt (II) (trimethylsilyl)methylene

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Synthesis and Structural Characterization of Bis(μ$_{2}$-Iodo)-Bis(Diethyl Ether)-(N-N′-(Bis(2,6-Diisopropylphenyl)Pentane-2,4-Diketiminato)-Lithium-Chromium, a Cr(II) (β-Diketiminato) Complex with a Coordinated LiI Salt

Synthesis and Crystal Structures of the Derivatives of Butyrate and 1,3-Dioxane; Allyl 2-acetyl-3-(phenylamino)butanoate, 2,6-Dimethyl N-(4-methylphenyl)-1,3-dioxan-4-amine and N-(3,5-Diflourophenyl)-2,6-dimethyl-1,3-dioxan-4-amine

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Synthesis and Characterization of the Adducts of Bis(O-amyldithiocarbonato)nickel(II) with Nitrogen Donors and X-ray Structure of Bis(O-amyldithiocarbonato)bis(3,5-dimethylpyridine)nickel(II)

Ring Puckering in Chloride-[N,N′-Bis(2,6-Diisopropylphenyl)-2,2,6,6-Tetramethylheptane-3,5-Diiminato]Tin(II)

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Ring Puckering in Chloride-[N,N′-Bis(2,6-Diisopropylphenyl)-2,2,6,6-Tetramethylheptane-3,5-Diiminato]Tin(II)