NDLI: Utilizing Perylene in New Organic Donor–Acceptor Materials: Highlighting the Synthesis, Structure and Physical Properties of Perylene-pDNB and Perylene-TCNP

Content Provider	Springer Nature Link
Author	Kimball, Dylan Munns, Raechel Fisher, Steven P. Bartolo, Mark Valdez, Jose Teat, Simon J. Tsui, Stephen Reinheimer, Eric W.
Copyright Year	2015
Abstract	In this communication, we present the syntheses, structure, infrared (IR) spectroscopic, and electronic transport properties for two new Perylene-containing donor–acceptor complexes, Perylene-pDNB (1) and Perylene-TCNP (2). The 2:1 complex with pDNB, complex 1, crystallizes in the triclinic space group $$ P\bar{1} $$ with cell dimensions a = 7.7488(12) Å, b = 9.7125(15) Å, c = 10.6864(17) Å, α = 80.829(7)°, β = 84.893(7)° and γ = 89.495(6)°, while complex 2, the 1:1 complex with TCNP, crystallizes in the orthorhombic space group Cmca with a = 18.264(4) Å, b = 7.405(2) Å and c = 14.674(3) Å. Structural features of the constituent donor and acceptor molecules were compared to those for the free components and, when coupled with IR spectroscopic measurements, suggested that both complexes contained neutral components. This conclusion was further supported by electronic transport measurements that revealed both complexes to be insulators.Herein we present the structure and both the IR spectroscopic and transport properties for new donor–acceptor complexes coupling Perylene with the acceptors para-dinitrobenzene (pDNB) and tetracyanopyrazine (TCNP).
Starting Page	169
Ending Page	177
Page Count	9
File Format	PDF
ISSN	10741542
Journal	Journal of Chemical Crystallography
Volume Number	45
Issue Number	4
e-ISSN	15728854
Language	English
Publisher	Springer US
Publisher Date	2015-03-25
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Perylene Organocyanide Charge transfer Crystal structure Organometallic Chemistry Crystallography Physical Chemistry Inorganic Chemistry
Content Type	Text
Resource Type	Article
Subject	Chemistry Condensed Matter Physics

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