NDLI: Synthesis and Crystal Structure of a New Binuclear Samarium Complex with Salicylate

Content Provider	Springer Nature Link
Author	Wang, Jun Fan, Jun Zhang, Wei guang Wang, Zhi hong Tan, Jing bo
Copyright Year	2009
Abstract	A new binuclear samarium complex, (HPhen)$_{2}$[Sm$_{2}$(Hsal)$_{8}$(H$_{2}$O)$_{2}$] · 2H$_{2}$O (Hsal = o-HOC$_{6}$H$_{4}$CO$_{2}$ $^{−}$, Phen = 1,10-phenanthroline) was synthesized under hydrothermal condition. Single crystal X-ray analysis reveals that it crystallizes in triclinic, P−1 space group with a = 9.7012(19) Å, b = 14.372(3) Å, c = 14.823(3) Å, α = 68.38(3)°, β = 88.16(3)°, γ = 79.54(3)°, V = 1,888.0(7) Å$^{3}$, Z = 1, μ = 1.629, F(000) = 922. In the dimeric anion [Sm$_{2}$(Hsal)$_{8}$(H$_{2}$O)$_{2}$]$^{2−}$, the two Sm(III) ions are connected by four bidentate bridging salicylate ligands. Each Sm(III) ion is coordinated to eight oxygen atoms, seven from six salicylate ligands, one from one coordinated water molecule. The salicylate molecules adopt three kinds of coordination mode, bidentate bridging, chelating, and monodentate. The mono-protonated 1,10-phenanthroline does not coordinate to the central atom directly. Intermolecular hydrogen bonds and π–π stacking interactions between parallel aromatic rings result in the formation of a two-dimensional supramolecular network.In the dinuclear compound (HPhen)$_{2}$[Sm$_{2}$(Hsal)$_{8}$(H$_{2}$O)$_{2}$] · 2H$_{2}$O (Hsal = o-HOC$_{6}$H$_{4}$CO$_{2}$ $^{−}$, Phen = 1,10-phenanthroline), intermolecular hydrogen bonds and π–π stacking interactions between parallel aromatic rings result in the formation of a two-dimensional supramolecular network.
Starting Page	585
Ending Page	588
Page Count	4
File Format	PDF
ISSN	10741542
Journal	Journal of Chemical Crystallography
Volume Number	39
Issue Number	8
e-ISSN	15728854
Language	English
Publisher	Springer US
Publisher Date	2009-03-04
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Samarium Salicylate Hydrothermal synthesis Crystal structure Inorganic Chemistry Physical Chemistry Crystallography Organometallic Chemistry
Content Type	Text
Resource Type	Article
Subject	Chemistry Condensed Matter Physics

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Synthesis and crystal structure of a binuclear maleatocopper(II) complex with phenanthroline

Synthesis, Crystal Structure of a New Co(II) Complex with Pyrazine-2,3,5,6-tetracarboxylic Acid

Synthesis and Crystal Structures of Two Binuclear Lanthanide [Ln = Pr, Dy] Complexes with 4-Quinolineacarboxylate

Synthesis and Crystal Structure of the New Samarium Oxyhydroxide, SmO(OH)

Synthesis, Crystal Structure and Magnetic Property of a One-Dimensional Samarium(III) Coordination Polymer

A dinuclear cyano-bridged complex based on hexacyanoferrate(III) and samarium(III) nitrate: synthesis and crystal structure

A Binuclear Ag(I) Complex Based on a Tripodal Ligand Tris(2-Benzimidazolylmethyl)amine: Synthesis and Characterization

Hydrothermal synthesis and crystal structure of a new europium fumarate compound

Synthesis and crystal structure of a silver(I) complex with dithioether ligand

Synthesis and Crystal Structure of a New Binuclear Samarium Complex with Salicylate

Similar Documents

Synthesis and crystal structure of a binuclear maleatocopper(II) complex with phenanthroline

Synthesis, Crystal Structure of a New Co(II) Complex with Pyrazine-2,3,5,6-tetracarboxylic Acid

Synthesis and Crystal Structures of Two Binuclear Lanthanide [Ln = Pr, Dy] Complexes with 4-Quinolineacarboxylate

Synthesis and Crystal Structure of the New Samarium Oxyhydroxide, SmO(OH)

Synthesis, Crystal Structure and Magnetic Property of a One-Dimensional Samarium(III) Coordination Polymer

A dinuclear cyano-bridged complex based on hexacyanoferrate(III) and samarium(III) nitrate: synthesis and crystal structure

A Binuclear Ag(I) Complex Based on a Tripodal Ligand Tris(2-Benzimidazolylmethyl)amine: Synthesis and Characterization

Hydrothermal synthesis and crystal structure of a new europium fumarate compound

Synthesis and crystal structure of a silver(I) complex with dithioether ligand

Synthesis and Crystal Structure of a New Binuclear Samarium Complex with Salicylate