NDLI: Thermodynamic stability of C$_{3}$H$_{8}$ hydrate of cubic structure IV using lattice dynamics

Content Provider	Springer Nature Link
Author	Souissi, Maaouia Belosludov, Rodion V. Subbotin, Oleg S. Mizuseki, Hiroshi Kawazoe, Yoshiyuki Belosludov, Vladimir R.
Copyright Year	2010
Abstract	The thermodynamic properties of propane clathrate hydrate with cubic structure IV were studied using a method based on the solid solution theory of van der Waals and Platteeuw but allows one to take into account the influence of guest molecules on the host lattice and guest-guest interactions. The free energies, equations of state, and chemical potentials of this hydrate were estimated using this approach. The proposed theory was used for construction of “guest gas–hydrate–ice I$_{h}$” equilibrium curves of propane hydrates. It was found that the water framework of structure IV was dynamically stable and that the fully C$_{3}$H$_{8}$ filled structure was thermodynamically stable in the region of pressure from 43 to 50 MPa as compared with the hexagonal ice. The formation pressure of propane hydrate with structure IV is higher than that of propane hydrate with cubic structure II. However, a structural transformation from structure II to IV of propane hydrate was estimated under a pressure of 78 MPa at 290 K.
Starting Page	281
Ending Page	286
Page Count	6
File Format	PDF
ISSN	09230750
Journal	Journal of Inclusion Phenomena and Macrocyclic Chemistry
Volume Number	69
Issue Number	1-2
e-ISSN	15731111
Language	English
Publisher	Springer Netherlands
Publisher Date	2010-08-20
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Thermodynamic stability sIV clathrate hydrate C$_{3}$H$_{8}$ Lattice dynamics Crystallography Food Science Organic Chemistry
Content Type	Text
Resource Type	Article
Subject	Chemistry Condensed Matter Physics Food Science

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