NDLI: CGO-based electrochemical catalysts for low temperature combustion of propene

Content Provider	Springer Nature Link
Author	Karoum, R. Roche, V. Pirova, C. Vannier, Rose elle Billard, A. Verux, P.
Copyright Year	2010
Abstract	This study has shown that the phenomenon of electrochemical promotion of catalysis or NEMCA effect can be used to activate a metal catalyst for the propene deep oxidation in the presence of water in the feed and in both stoichiometric and lean-burn conditions. The electrochemical catalysts were based on sputtered Pt films interfaced with gadolinium-doped ceria solid electrolyte. This system allows implementing NEMCA effect at quite low temperatures and electrochemical activation of propene deep oxidation was evidenced at temperatures as low as 190 °C. In addition, a new design of electrochemical catalysts was proposed by depositing a interlayer of strontium-doped lanthanum manganite between the CGO dense support and an ultra-thin coating of Pt. This concept allows to drastically decrease the Pt loading since the electronic conductivity is ensured by the perovskite layer.
Starting Page	1867
Ending Page	1873
Page Count	7
File Format	PDF
ISSN	0021891X
Journal	Journal of Applied Electrochemistry
Volume Number	40
Issue Number	10
e-ISSN	15728838
Language	English
Publisher	Springer Netherlands
Publisher Date	2010-06-12
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Electrochemical promotion EPOC NEMCA effect Electrochemical catalyst CGO Strontium-doped lanthanum manganite interlayer Propene combustion Wet condition Industrial Chemistry/Chemical Engineering Physical Chemistry Electrochemistry
Content Type	Text
Resource Type	Article
Subject	Materials Chemistry Chemical Engineering Electrochemistry

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