NDLI: Chemical reducing pedoenvironment in a peatland influenced by hematitic phyllite lithology in the southern Espinhaço chain, Brazil

Content Provider	Springer Nature Link
Author	Paesa, Andrea Silva, Alexandre Christófaro Ivashita, Flávio Francisco Cerqueira Machado Flavio Sives, Carla Fabiana Sives, Flávio Mercader, Roberto Carlos Fabris, José Domingos
Copyright Year	2013
Abstract	A peatland in Pinheiro, Diamantina City, Minas Gerais State - Brazil, was sampled at different depths of two profiles with diverse vegetation coverings (grassland field and bush) in order to collect materials that might reflect changes in the chemical states of iron over the peat formation coming from original minerals such as hematitic phyllite surrounding the boggy pedon. Samples collected were chemically, structurally and magnetically characterized. The results show that both series of peats are composed of organic matter and minerals such as quartz, kaolinite, gibbsite, rutile and muscovite. Deeper layers present only quartz. Mössbauer spectroscopy shows that iron is present in both electron states, Fe2+ and Fe3+, under both vegetations, each valence appearing in the spectra in the form of a discrete doublet. No hyperfine magnetic splitting was observed in any spectrum at room temperature. The Mössbauer subspectral area of Fe2+ tended to increase from the upper to deeper layers. Magnetic measurements reveal that the magnetic response of the surface samples is the highest, displaying a sharp decrease below 15 cm and that the magnetic signal is a superposition of (super)paramagnetic and ferrimagnetic contributions. Samples from the grassland field also show a diamagnetic component for the deeper layers.
Starting Page	585
Ending Page	592
Page Count	8
File Format	PDF
ISSN	03043843
Journal	Hyperfine Interactions
Volume Number	226
Issue Number	1-3
e-ISSN	15729540
Language	English
Publisher	Springer International Publishing
Publisher Date	2013-12-03
Publisher Place	Cham
Access Restriction	Subscribed
Subject Keyword	Peatland Iron oxidation states Soil organic matter Hematitic phyllite Nuclear Physics, Heavy Ions, Hadrons Atomic, Molecular, Optical and Plasma Physics Condensed Matter Physics Surfaces and Interfaces, Thin Films
Content Type	Text
Resource Type	Article
Subject	Nuclear and High Energy Physics Atomic and Molecular Physics, and Optics Physical and Theoretical Chemistry Condensed Matter Physics

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