NDLI: Mössbauer and XRD study of pulse plated Sn-Fe, Sn-Ni and Sn-Ni-Fe electrodeposited alloys

Content Provider	Springer Nature Link
Author	Stichleutner, S. Lak, G. B. Kuzmann, E. Chisholm, C. U. El Sharif, M. Homonnay, Z. Sziráki, L.
Copyright Year	2013
Abstract	Effect of pulse plating on novel electrodeposited binary and ternary amorphous alloys was studied by 57Fe and 119Sn conversion electron Mössbauer spectroscopy and X-ray diffraction. Our results show that by adjusting the parameters of pulse plating a fine tuning of the composition and current efficiency can be achieved within these systems. On the contrary to direct current deposition, where the crystalline FeSn2 phase dominates, pulse plating technique produces amorphous Sn-Fe alloy phases, of which the ferromagnetic phase is the dominant one. Both, direct current and pulse plated Sn-Ni deposits consist of paramagnetic alloy phases and minor amounts of β-Sn, the occurrence of which correlates with the tin content of the samples. Pulse plated Sn-Ni-Fe coatings are amorphous and in a dominantly ferromagnetic state, however at long on- and off-pulse times and high peak current density the paramagnetic state dominates and β-Sn segregation also occurs.
Starting Page	15
Ending Page	25
Page Count	11
File Format	PDF
ISSN	03043843
Journal	Hyperfine Interactions
Volume Number	226
Issue Number	1-3
e-ISSN	15729540
Language	English
Publisher	Springer International Publishing
Publisher Date	2013-10-25
Publisher Place	Cham
Access Restriction	Subscribed
Subject Keyword	Sn-Fe and Sn-Ni binary alloys Sn-Ni-Fe ternary alloys Electrodeposition Amorphous alloys 57Fe and 119Sn Mössbauer spectroscopy Nuclear Physics, Heavy Ions, Hadrons Atomic, Molecular, Optical and Plasma Physics Condensed Matter Physics Surfaces and Interfaces, Thin Films
Content Type	Text
Resource Type	Article
Subject	Nuclear and High Energy Physics Atomic and Molecular Physics, and Optics Physical and Theoretical Chemistry Condensed Matter Physics

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