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| Content Provider | Springer Nature Link |
|---|---|
| Author | El Sharif, M. Chisholm, C. U. Kuzmann, E. Sziráki, L. Stichleutner, S. Homonnay, Z. Süvegh, K. Vértes, A. |
| Copyright Year | 2009 |
| Abstract | This study involved the use of a flow circulation cell, using varying circulation rates as a room temperature process (20°C). Mössbauer and XRD analysis were conducted to ascertain whether amorphous or microcrystalline structures could be obtained at 20°C using a range of current densities. Amorphous or microcrystalline structures of Sn–Fe and Sn–Co–Fe have potentially important industrial applications for energy efficient cells, for use as high performance electrodes in lithium batteries, as environmentally acceptable corrosion resistant materials and are derived from an energy efficient environmentally friendly electrolyte process which would be acceptable as an industrial process. $^{\it 57}Fe$ and $^{\it 119}Sn$ Mössbauer investigations supported by XRD analysis confirmed that the room temperature flow circulation cell gave rise to previously unknown non-equilibrium amorphous structures which do not occur in the corresponding thermally prepared alloys as shown in the thermal equilibrium diagrams. Mössbauer analysis shows these alloys to be both amorphous and ferromagnetic. It is shown that the flow circulation cell used at 20°C based on the environmentally friendly gluconate bath reported gives amorphous based Sn–Fe and Sn–Co–Fe alloys over a useful range of current densities facilitated by using a range of circulation rates. |
| Starting Page | 1 |
| Ending Page | 12 |
| Page Count | 12 |
| File Format | |
| ISSN | 03043843 |
| Journal | Hyperfine Interactions |
| Volume Number | 192 |
| Issue Number | 1-3 |
| e-ISSN | 15729540 |
| Language | English |
| Publisher | Springer Netherlands |
| Publisher Date | 2009-04-02 |
| Publisher Place | Dordrecht |
| Access Restriction | Subscribed |
| Subject Keyword | Electrodeposition Sn–Fe Sn–Co–Fe Mössbauer spectroscopy X-ray diffraction Surfaces and Interfaces, Thin Films Condensed Matter Atoms, Molecules, Clusters and Plasmas Nuclear Physics, Heavy Ions, Hadrons |
| Content Type | Text |
| Resource Type | Article |
| Subject | Nuclear and High Energy Physics Atomic and Molecular Physics, and Optics Physical and Theoretical Chemistry Condensed Matter Physics |
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