NDLI: Nanocomposite-based lignocellulosic fibers 1. Thermal stability of modified fibers with clay-polyelectrolyte multilayers

Content Provider	Springer Nature Link
Author	Lin, Zhiyuan Renneckar, Scott Hindman, Daniel P.
Copyright Year	2007
Abstract	The layer-by-layer (LbL) assembly process of creating highly structured thin films derived from layers of polyelectrolytes and nanoparticles was adopted in this study to modify the surface of lignocellulosic fibers. Aqueous dispersions of clay nanoplatelets were created with ultrasonication and characterized with dynamic light scattering and atomic force microscopy in which confirmed the presence of individual clay nanoplatelets. Film thickness of never-dried clay and poly(diallyldimethylammonium chloride) (PDDA) multilayers was studied with a quartz crystal microbalance with dissipation monitoring (QCM-D). Using identical LbL deposition parameters, a slurry of steam-exploded wood fibers was modified by alternate adsorption of PDDA and clay with multiple rinsing steps after each adsorption cycle. Zeta potential measurements were used to characterize the fiber surface charges after each adsorption step while SEM images revealed that the LbL film masked the cellulose microfibril structure. Using a thermogravimetric analyzer, LbL modified steam-exploded wood fibers were observed to attain increased thermal stability relative to the unmodified material tested in both air and nitrogen atmospheres. Significant char for the LbL clay coated steam-exploded wood suggests the multilayer film serves as a barrier creating an insulating layer to prevent further decomposition of the material. This nanotechnology may have a positive impact on the processing of lignocellulosic fibers in thermoplastic matrices, designing of paper-based overlays for building products, and modification of cellulosic fibers for textiles.
Starting Page	333
Ending Page	346
Page Count	14
File Format	PDF
ISSN	09690239
Journal	Cellulose
Volume Number	15
Issue Number	2
e-ISSN	1572882X
Language	English
Publisher	Springer Netherlands
Publisher Date	2007-10-24
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Fiber modification Layer-by-layer Polyelectrolyte multilayers (PEM) Pulp Self-assembly Thermal degradation Polymer Sciences Organic Chemistry Physical Chemistry Bioorganic Chemistry
Content Type	Text
Resource Type	Article
Subject	Polymers and Plastics

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Nanocomposite-based lignocellulosic fibers 3: polyelectrolyte adsorption onto heterogeneous fiber surfaces

Surface modification of cellulose fibers with layer-by-layer self-assembly of lignosulfonate and polyelectrolyte: effects on fibers wetting properties and paper strength

Surface modification of lignocellulosic fibers using high-frequency ultrasound

Biointeractive antibacterial fibres using polyelectrolyte multilayer modification

Photodiodes based on wood pulp fiber networks

Fragment analysis of different size-reduced lignocellulosic pulps by hydrodynamic fractionation

Preparation of fine fiber sheets from recycled pulp fibers using aqueous counter collision

Direct grafting modification of pulp in ionic liquids and self-assembly behavior of the graft copolymers

Physicochemical and thermal properties of lignocellulosic fiber from sugar palm fibers: effect of treatment

Nanocomposite-based lignocellulosic fibers 1. Thermal stability of modified fibers with clay-polyelectrolyte multilayers

Similar Documents

Nanocomposite-based lignocellulosic fibers 3: polyelectrolyte adsorption onto heterogeneous fiber surfaces

Surface modification of cellulose fibers with layer-by-layer self-assembly of lignosulfonate and polyelectrolyte: effects on fibers wetting properties and paper strength

Surface modification of lignocellulosic fibers using high-frequency ultrasound

Biointeractive antibacterial fibres using polyelectrolyte multilayer modification

Photodiodes based on wood pulp fiber networks

Fragment analysis of different size-reduced lignocellulosic pulps by hydrodynamic fractionation

Preparation of fine fiber sheets from recycled pulp fibers using aqueous counter collision

Direct grafting modification of pulp in ionic liquids and self-assembly behavior of the graft copolymers

Physicochemical and thermal properties of lignocellulosic fiber from sugar palm fibers: effect of treatment

Nanocomposite-based lignocellulosic fibers 1. Thermal stability of modified fibers with clay-polyelectrolyte multilayers