NDLI: Steady-shear and viscoelastic properties of cellulose nanofibril

Content Provider	Springer Nature Link
Author	Liu, Yingxin Gordeyeva, Korneliya Bergström, Lennart
Copyright Year	2017
Abstract	We have investigated the steady-shear and viscoelastic properties of composite dispersions of cellulose nanofibrils (CNFs) with medium or high charge density and two different nanoclays, viz. rod-like sepiolite or plate-like bentonite. Aqueous dispersions of CNFs with medium charge density displayed significantly lower steady-state viscosity and storage modulus but higher gelation threshold compared with CNFs with high charge density. Dynamic light scattering (DLS) results showed that the apparent hydrodynamic radius of bentonite particles increased when CNFs were added, implying that CNFs adsorbed onto the amphoteric edges of the plate-like bentonite particles. The sepiolite network in CNF–sepiolite dispersions was relatively unaffected by addition of small amounts of CNFs, and DLS showed that the hydrodynamic radius of sepiolite did not change when CNFs were added. Addition of CNFs at concentrations above the gelation threshold resulted in drastic decrease of the steady-shear viscosity of the sepiolite dispersion, suggesting that the sepiolite network disintegrates and the rod-like clay particles are aligned also at low shear rate. The relative change in the rheological properties of the clay-based dispersions was always greater on addition of CNFs with high compared with medium charge density. This study provides insight into how the rheology of CNF–nanoclay dispersions depends on both the nanoclay morphology and the interactions between the nanoclay and nanocellulose particles, being of relevance to processing of nanocellulose–clay composites.
Starting Page	1815
Ending Page	1824
Page Count	10
File Format	PDF
ISSN	09690239
Journal	Cellulose
Volume Number	24
Issue Number	4
e-ISSN	1572882X
Language	English
Publisher	Springer Netherlands
Publisher Date	2017-02-08
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Cellulose nanofibrils Nanocellulose dispersions Bentonite Sepiolite Viscoelasticity Bioorganic Chemistry Physical Chemistry Organic Chemistry Polymer Sciences Ceramics, Glass, Composites, Natural Materials Sustainable Development
Content Type	Text
Resource Type	Article
Subject	Polymers and Plastics

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