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| Content Provider | Springer Nature Link |
|---|---|
| Author | Xu, Siquan Yan, Xiaopei Bu, Quan Xia, Haian |
| Copyright Year | 2017 |
| Abstract | A series of carbon nanotube (CNT)-supported monometallic Pd and bimetallic Pd–Fe catalysts were synthesized and employed for catalytic hydrogenolysis of cellulose into polyols, including hexitol, ethylene glycol (EG), 1,2-propanediol (1,2-PG), and glycerol (Gly). The physicochemical properties of the catalysts were characterized by nitrogen physical adsorption measurements, X-ray diffraction analysis, transmission electron microscopy, and X-ray photoelectron spectroscopy. The total yield of hexitol, EG, 1,2-PG, and Gly in hydrolytic hydrogenation of cellulose was 37, 55, and 53% for Pd/CNTs, Pd–Fe/CNTs (Pd:Fe = 1:1), and Pd–Fe/CNTs (Pd:Fe = 1:2), respectively. Addition of Fe to Pd significantly modified the physicochemical properties of the nanoparticles and their catalytic performance, especially regarding hexitol selectivity. The promoting effect of Fe, especially for hexitol selectivity, compared with the monometallic catalyst is due to the fact that incorporation of Fe may stabilize Pd0 nanoparticles and lead to downshift of the d-band center of Pd metal nanoparticles by charge transfer from Fe to Pd. Recycling experimental results showed that leaching of Fe resulted in a significant decrease in the hexitol yield obtained using the Pd–Fe/CNTs after the first recycle, further demonstrating that Fe element plays a promoting role for hexitol formation. |
| Starting Page | 2403 |
| Ending Page | 2413 |
| Page Count | 11 |
| File Format | |
| ISSN | 09690239 |
| Journal | Cellulose |
| Volume Number | 24 |
| Issue Number | 6 |
| e-ISSN | 1572882X |
| Language | English |
| Publisher | Springer Netherlands |
| Publisher Date | 2017-04-08 |
| Publisher Place | Dordrecht |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Cellulose Polyols Hydrogenolysis Bimetallic d-Band Bioorganic Chemistry Physical Chemistry Organic Chemistry Polymer Sciences Ceramics, Glass, Composites, Natural Materials Sustainable Development |
| Content Type | Text |
| Resource Type | Article |
| Subject | Polymers and Plastics |
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