NDLI: Synthesis of Acetoaldehyde, Acetic Acid, and Others by the Dehydrogenation and Oxidation of Ethanol

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Catalysis Surveys from Asia : Volume 15, Issue 1, March 2011

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Synthesis of Acetoaldehyde, Acetic Acid, and Others by the Dehydrogenation and Oxidation of Ethanol

Content Provider	Springer Nature Link
Author	Takei, Takashi Iguchi, rihiko Haruta, Masatake
Copyright Year	2011
Abstract	Following gradual shift of primary resources from fossil towards renewable ones in chemical industry, biomass based ethanol has been attracting growing interests as a fuel to replace gasoline and as a chemical feed stock to replace ethylene. This paper reviews major work reported in the last 10 years for the production of acetaldehyde, acetic acid, and other related compounds from ethanol. At present acetic acid can be industrially produced more economically from methanol than from ethylene, the production of acetic acid from ethanol is not profitable. Acetaldehyde, which is more expensive than ethanol, can be selectively produced in gas phase by dehydrogenation over supported Cu catalysts and by oxidation with O2 over V and Mo based oxides. It is noteworthy that gold nanoparticles deposited on basic and acidic metal oxides are highly selective to acetaldehyde by oxidation with O2. Acetic acid can be produced in water solvent over Au catalysts supported on MgAl2O4 or on Cu doped NiO, while in gas phase over Mo–V–Nb mixed oxides combined with TiO2 colloids.
Starting Page	80
Ending Page	88
Page Count	9
File Format	PDF
ISSN	15711013
Journal	Catalysis Surveys from Asia
Volume Number	15
Issue Number	2
e-ISSN	15749266
Language	English
Publisher	Springer US
Publisher Date	2011-03-03
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Ethanol Acetaldehyde Acetic acid Ethyl acetate Ethylene oxide Gold catalysts Copper catalysts Mo or V based oxides Catalysis Industrial Chemistry/Chemical Engineering Physical Chemistry Characterization and Evaluation of Materials
Content Type	Text
Resource Type	Article
Subject	Chemistry Catalysis

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