NDLI: A Non-sodium Synthesis of Highly Ordered V-MCM-41 and Its Catalytic Application in Isomerization

Content Provider	Springer Nature Link
Author	Hu, Shuangquan Liu, Dapeng Li, Lusi Borgna, Armando Yang, Yanhui
Copyright Year	2009
Abstract	A rapid non-sodium process was developed to synthesize highly ordered V-MCM-41 mesoporous materials with atomic level dispersed vanadium species. NH3·H2O instead of NaOH was used to maintain the moderately basic synthesis condition. The characterization results of N2 physisorption and XRD showed that the synthesized samples had highly ordered hexagonal structure. UV–Vis, UV-Raman, and EPR spectra provided evidence that most vanadium ions were tetrahedrally incorporated into the framework of siliceous MCM-41. The NH3-TPD proved the mild acidity of V-MCM-41 due to the incorporation of vanadium cations. The most important variables were structural order and vanadium loading which can be controlled easily by changing synthesis variables in such a way that collapse of the V-MCM-41structure did not occur. The synthesized V-MCM-41 catalysts successfully catalyzed the isomerization of heptene. High conversion and isomer selectivity were achieved with good catalytic stability. The structure of V-MCM-41 can be well preserved after reaction.
Starting Page	478
Ending Page	485
Page Count	8
File Format	PDF
ISSN	1011372X
Journal	Catalysis Letters
Volume Number	129
Issue Number	3-4
e-ISSN	1572879X
Language	English
Publisher	Springer US
Publisher Date	2009-01-09
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	V-MCM-41 Non-sodium Isomerization Pharmacy Industrial Chemistry/Chemical Engineering Physical Chemistry Catalysis
Content Type	Text
Resource Type	Article
Subject	Chemistry Catalysis

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

A Non-sodium Synthesis of Highly Ordered V-MCM-41 and Its Catalytic Application in Isomerization

Synthesis of V-MCM-41 by template-ion exchange method and its catalytic properties in propane oxidative dehydrogenation

Radius of Curvature Effect on the Selective Oxidation of Cyclohexene Over Highly Ordered V-MCM-41

Isomerization of Norbornadiene to Quadricyclane Using Ti-Containing MCM-41 as Photocatalysts

Characterisation and catalytic properties of MCM-41 and Pd/MCM-41 materials

Photo-Assisted Synthesis of V-MCM-41 Under UV Light Irradiation

Skeletal Isomerization of n-Pentane over Platinum-Promoted Tungstophosphoric Acid Supported on MCM-41

Cu–H-MCM-41, H-MCM-41 and Na-MCM-41 Mesoporous Molecular Sieve Catalysts for Isomerization of 1-Butene to Isobutene

Catalytic reduction of NOx over transition-metal-containing MCM-41

A Non-sodium Synthesis of Highly Ordered V-MCM-41 and Its Catalytic Application in Isomerization

Similar Documents

A Non-sodium Synthesis of Highly Ordered V-MCM-41 and Its Catalytic Application in Isomerization

Synthesis of V-MCM-41 by template-ion exchange method and its catalytic properties in propane oxidative dehydrogenation

Radius of Curvature Effect on the Selective Oxidation of Cyclohexene Over Highly Ordered V-MCM-41

Isomerization of Norbornadiene to Quadricyclane Using Ti-Containing MCM-41 as Photocatalysts

Characterisation and catalytic properties of MCM-41 and Pd/MCM-41 materials

Photo-Assisted Synthesis of V-MCM-41 Under UV Light Irradiation

Skeletal Isomerization of n-Pentane over Platinum-Promoted Tungstophosphoric Acid Supported on MCM-41

Cu–H-MCM-41, H-MCM-41 and Na-MCM-41 Mesoporous Molecular Sieve Catalysts for Isomerization of 1-Butene to Isobutene

Catalytic reduction of NOx over transition-metal-containing MCM-41

A Non-sodium Synthesis of Highly Ordered V-MCM-41 and Its Catalytic Application in Isomerization